Recent State and Challenges in Spectroelectrochemistry with Its Applications in Microfluidics
This review paper presents the recent developments in spectroelectrochemical (SEC) technologies. The coupling of spectroscopy and electrochemistry enables SEC to do a detailed and comprehensive study of the electron transfer kinetics and vibrational spectroscopic fingerprint of analytes during elect...
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Format: | Article |
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MDPI AG
2023-03-01
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Series: | Micromachines |
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Online Access: | https://www.mdpi.com/2072-666X/14/3/667 |
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author | Zhenglong Li Charmi Chande Yu-Hsuan Cheng Sagnik Basuray |
author_facet | Zhenglong Li Charmi Chande Yu-Hsuan Cheng Sagnik Basuray |
author_sort | Zhenglong Li |
collection | DOAJ |
description | This review paper presents the recent developments in spectroelectrochemical (SEC) technologies. The coupling of spectroscopy and electrochemistry enables SEC to do a detailed and comprehensive study of the electron transfer kinetics and vibrational spectroscopic fingerprint of analytes during electrochemical reactions. Though SEC is a promising technique, the usage of SEC techniques is still limited. Therefore, enough publicity for SEC is required, considering the promising potential in the analysis fields. Unlike previously published review papers primarily focused on the relatively frequently used SEC techniques (ultraviolet-visible SEC and surface-enhanced Raman spectroscopy SEC), the two not-frequently used but promising techniques (nuclear magnetic resonance SEC and dark-field microscopy SEC) have also been studied in detail. This review paper not only focuses on the applications of each SEC method but also details their primary working mechanism. In short, this paper summarizes each SEC technique’s working principles, current applications, challenges encountered, and future development directions. In addition, each SEC technique’s applicative research directions are detailed and compared in this review work. Furthermore, integrating SEC techniques into microfluidics is becoming a trend in minimized analysis devices. Therefore, the usage of SEC techniques in microfluidics is discussed. |
first_indexed | 2024-03-11T06:09:33Z |
format | Article |
id | doaj.art-b1e1bc297f3a446ea3770b4ae1519671 |
institution | Directory Open Access Journal |
issn | 2072-666X |
language | English |
last_indexed | 2024-03-11T06:09:33Z |
publishDate | 2023-03-01 |
publisher | MDPI AG |
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series | Micromachines |
spelling | doaj.art-b1e1bc297f3a446ea3770b4ae15196712023-11-17T12:44:00ZengMDPI AGMicromachines2072-666X2023-03-0114366710.3390/mi14030667Recent State and Challenges in Spectroelectrochemistry with Its Applications in MicrofluidicsZhenglong Li0Charmi Chande1Yu-Hsuan Cheng2Sagnik Basuray3Department of Chemical and Materials Engineering, New Jersey Institute of Technology, Newark, NJ 07102, USADepartment of Chemical and Materials Engineering, New Jersey Institute of Technology, Newark, NJ 07102, USADepartment of Chemical and Materials Engineering, New Jersey Institute of Technology, Newark, NJ 07102, USADepartment of Chemical and Materials Engineering, New Jersey Institute of Technology, Newark, NJ 07102, USAThis review paper presents the recent developments in spectroelectrochemical (SEC) technologies. The coupling of spectroscopy and electrochemistry enables SEC to do a detailed and comprehensive study of the electron transfer kinetics and vibrational spectroscopic fingerprint of analytes during electrochemical reactions. Though SEC is a promising technique, the usage of SEC techniques is still limited. Therefore, enough publicity for SEC is required, considering the promising potential in the analysis fields. Unlike previously published review papers primarily focused on the relatively frequently used SEC techniques (ultraviolet-visible SEC and surface-enhanced Raman spectroscopy SEC), the two not-frequently used but promising techniques (nuclear magnetic resonance SEC and dark-field microscopy SEC) have also been studied in detail. This review paper not only focuses on the applications of each SEC method but also details their primary working mechanism. In short, this paper summarizes each SEC technique’s working principles, current applications, challenges encountered, and future development directions. In addition, each SEC technique’s applicative research directions are detailed and compared in this review work. Furthermore, integrating SEC techniques into microfluidics is becoming a trend in minimized analysis devices. Therefore, the usage of SEC techniques in microfluidics is discussed.https://www.mdpi.com/2072-666X/14/3/667spectroelectrochemistryultraviolet-visible SECsurface-enhanced Raman spectroscopy SECnuclear magnetic resonance SECdark-field microscopy SECmicrofluidics |
spellingShingle | Zhenglong Li Charmi Chande Yu-Hsuan Cheng Sagnik Basuray Recent State and Challenges in Spectroelectrochemistry with Its Applications in Microfluidics Micromachines spectroelectrochemistry ultraviolet-visible SEC surface-enhanced Raman spectroscopy SEC nuclear magnetic resonance SEC dark-field microscopy SEC microfluidics |
title | Recent State and Challenges in Spectroelectrochemistry with Its Applications in Microfluidics |
title_full | Recent State and Challenges in Spectroelectrochemistry with Its Applications in Microfluidics |
title_fullStr | Recent State and Challenges in Spectroelectrochemistry with Its Applications in Microfluidics |
title_full_unstemmed | Recent State and Challenges in Spectroelectrochemistry with Its Applications in Microfluidics |
title_short | Recent State and Challenges in Spectroelectrochemistry with Its Applications in Microfluidics |
title_sort | recent state and challenges in spectroelectrochemistry with its applications in microfluidics |
topic | spectroelectrochemistry ultraviolet-visible SEC surface-enhanced Raman spectroscopy SEC nuclear magnetic resonance SEC dark-field microscopy SEC microfluidics |
url | https://www.mdpi.com/2072-666X/14/3/667 |
work_keys_str_mv | AT zhenglongli recentstateandchallengesinspectroelectrochemistrywithitsapplicationsinmicrofluidics AT charmichande recentstateandchallengesinspectroelectrochemistrywithitsapplicationsinmicrofluidics AT yuhsuancheng recentstateandchallengesinspectroelectrochemistrywithitsapplicationsinmicrofluidics AT sagnikbasuray recentstateandchallengesinspectroelectrochemistrywithitsapplicationsinmicrofluidics |