Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels

While biological fluoride ion channels display excellent F− conductivity and selectivity, designing synthetic analogues remains highly challenging. Here the authors show that zirconium-based metal–organic frameworks with F− binding sites and sub-1-nanometer channels exhibit ultrahigh F− conductivity...

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Main Authors: Xingya Li, Huacheng Zhang, Peiyao Wang, Jue Hou, Jun Lu, Christopher D. Easton, Xiwang Zhang, Matthew R. Hill, Aaron W. Thornton, Jefferson Zhe Liu, Benny D. Freeman, Anita J. Hill, Lei Jiang, Huanting Wang
Format: Article
Language:English
Published: Nature Portfolio 2019-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-10420-9
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author Xingya Li
Huacheng Zhang
Peiyao Wang
Jue Hou
Jun Lu
Christopher D. Easton
Xiwang Zhang
Matthew R. Hill
Aaron W. Thornton
Jefferson Zhe Liu
Benny D. Freeman
Anita J. Hill
Lei Jiang
Huanting Wang
author_facet Xingya Li
Huacheng Zhang
Peiyao Wang
Jue Hou
Jun Lu
Christopher D. Easton
Xiwang Zhang
Matthew R. Hill
Aaron W. Thornton
Jefferson Zhe Liu
Benny D. Freeman
Anita J. Hill
Lei Jiang
Huanting Wang
author_sort Xingya Li
collection DOAJ
description While biological fluoride ion channels display excellent F− conductivity and selectivity, designing synthetic analogues remains highly challenging. Here the authors show that zirconium-based metal–organic frameworks with F− binding sites and sub-1-nanometer channels exhibit ultrahigh F− conductivity and selectivity.
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spelling doaj.art-b1e61f0cd75e4bbc937d37ae7a0bd7af2022-12-21T18:00:42ZengNature PortfolioNature Communications2041-17232019-06-0110111210.1038/s41467-019-10420-9Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channelsXingya Li0Huacheng Zhang1Peiyao Wang2Jue Hou3Jun Lu4Christopher D. Easton5Xiwang Zhang6Matthew R. Hill7Aaron W. Thornton8Jefferson Zhe Liu9Benny D. Freeman10Anita J. Hill11Lei Jiang12Huanting Wang13Department of Chemical Engineering, Monash UniversityDepartment of Chemical Engineering, Monash UniversityDepartment of Mechanical Engineering, The University of MelbourneDepartment of Chemical Engineering, Monash UniversityDepartment of Chemical Engineering, Monash UniversityManufacturing, CSIRODepartment of Chemical Engineering, Monash UniversityDepartment of Chemical Engineering, Monash UniversityManufacturing, CSIRODepartment of Mechanical Engineering, The University of MelbourneDepartment of Chemical Engineering, The University of Texas at AustinManufacturing, CSIRODepartment of Chemical Engineering, Monash UniversityDepartment of Chemical Engineering, Monash UniversityWhile biological fluoride ion channels display excellent F− conductivity and selectivity, designing synthetic analogues remains highly challenging. Here the authors show that zirconium-based metal–organic frameworks with F− binding sites and sub-1-nanometer channels exhibit ultrahigh F− conductivity and selectivity.https://doi.org/10.1038/s41467-019-10420-9
spellingShingle Xingya Li
Huacheng Zhang
Peiyao Wang
Jue Hou
Jun Lu
Christopher D. Easton
Xiwang Zhang
Matthew R. Hill
Aaron W. Thornton
Jefferson Zhe Liu
Benny D. Freeman
Anita J. Hill
Lei Jiang
Huanting Wang
Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
Nature Communications
title Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
title_full Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
title_fullStr Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
title_full_unstemmed Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
title_short Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
title_sort fast and selective fluoride ion conduction in sub 1 nanometer metal organic framework channels
url https://doi.org/10.1038/s41467-019-10420-9
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