Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvate
The title compound, [Cd(C7H5O3)2(C10H8N2)2]·CH3OH, contains one monomeric seven-coordinate cadmium complex and one methanol solvate molecule. The CdII atom is coordinated to two 2,2′-bipyridyl ligands via the N atoms and to two salicylate anions (Hsal−) via t...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809054610 |
| _version_ | 1819349405137895424 |
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| author | Rymel Benrabah Bernard Viossat Alain Tomas Pascale Lemoine |
| author_facet | Rymel Benrabah Bernard Viossat Alain Tomas Pascale Lemoine |
| author_sort | Rymel Benrabah |
| collection | DOAJ |
| description | The title compound, [Cd(C7H5O3)2(C10H8N2)2]·CH3OH, contains one monomeric seven-coordinate cadmium complex and one methanol solvate molecule. The CdII atom is coordinated to two 2,2′-bipyridyl ligands via the N atoms and to two salicylate anions (Hsal−) via the carboxylate O atoms, which act as monodentate ligand for the one and bidentate ligand for the second. The CdII atom exhibits a {6 + 1} environment, approximately described as a distorted capped octahedron with the apical positions occupied by one of the two N atoms belonging to one bipyridyl ligand and one of the two carboxylate O atoms from the monodentate Hsal− ligand. Two intramolecular six-membered hydrogen-bonded rings are present, generated from interactions between the carboxylate and hydroxy groups of the salicylate ligands. There is one intermolecular hydrogen-bonding interaction involving the methanol solvent molecule and the carboxylate group from the monodentate Hsal− ligand. The crystal packing is governed by π–π stacking interactions [centroid–centroid distance = 3.783 (4) Å] which occur between bipyridyl ligands, by C—H...O and C—H...π interactions and by numerous van der Waals contacts. |
| first_indexed | 2024-12-24T19:00:00Z |
| format | Article |
| id | doaj.art-b20c725304464ac2b3f9b6c105178ac0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T19:00:00Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b20c725304464ac2b3f9b6c105178ac02022-12-21T16:43:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m156m15710.1107/S1600536809054610Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvateRymel BenrabahBernard ViossatAlain TomasPascale LemoineThe title compound, [Cd(C7H5O3)2(C10H8N2)2]·CH3OH, contains one monomeric seven-coordinate cadmium complex and one methanol solvate molecule. The CdII atom is coordinated to two 2,2′-bipyridyl ligands via the N atoms and to two salicylate anions (Hsal−) via the carboxylate O atoms, which act as monodentate ligand for the one and bidentate ligand for the second. The CdII atom exhibits a {6 + 1} environment, approximately described as a distorted capped octahedron with the apical positions occupied by one of the two N atoms belonging to one bipyridyl ligand and one of the two carboxylate O atoms from the monodentate Hsal− ligand. Two intramolecular six-membered hydrogen-bonded rings are present, generated from interactions between the carboxylate and hydroxy groups of the salicylate ligands. There is one intermolecular hydrogen-bonding interaction involving the methanol solvent molecule and the carboxylate group from the monodentate Hsal− ligand. The crystal packing is governed by π–π stacking interactions [centroid–centroid distance = 3.783 (4) Å] which occur between bipyridyl ligands, by C—H...O and C—H...π interactions and by numerous van der Waals contacts.http://scripts.iucr.org/cgi-bin/paper?S1600536809054610 |
| spellingShingle | Rymel Benrabah Bernard Viossat Alain Tomas Pascale Lemoine Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvate Acta Crystallographica Section E |
| title | Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvate |
| title_full | Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvate |
| title_fullStr | Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvate |
| title_full_unstemmed | Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvate |
| title_short | Bis(2,2′-bipyridyl-κ2N,N′)bis(2-hydroxybenzoato)-κO1;κ2O1,O1′-cadmium(II) methanol solvate |
| title_sort | bis 2 2 amp 8242 bipyridyl amp 954 2n n amp 8242 bis 2 hydroxybenzoato amp 954 o1 amp 954 2o1 o1 amp 8242 cadmium ii methanol solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809054610 |
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