Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate
In the title compound, Na+·C6H4BrClNO2S−·1.5H2O, one water molecule has crystallographically imposed twofold symmetry. The Na+ cation shows a pseudo-octahedral coordination provided by three O atoms of water molecules and three sulfonyl O atoms of different N-...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681102071X |
| Summary: | In the title compound, Na+·C6H4BrClNO2S−·1.5H2O, one water molecule has crystallographically imposed twofold symmetry. The Na+ cation shows a pseudo-octahedral coordination provided by three O atoms of water molecules and three sulfonyl O atoms of different N-bromo-2-chlorobenzenesulfonamidate anions. The S—N distance of 1.579 (6) Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O—H...Br, O—H...N and O—H...O hydrogen bonds. |
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| ISSN: | 1600-5368 |