Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate
In the title compound, Na+·C6H4BrClNO2S−·1.5H2O, one water molecule has crystallographically imposed twofold symmetry. The Na+ cation shows a pseudo-octahedral coordination provided by three O atoms of water molecules and three sulfonyl O atoms of different N-...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681102071X |
| _version_ | 1818321811934281728 |
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| author | B. Thimme Gowda Sabine Foro K. Shakuntala |
| author_facet | B. Thimme Gowda Sabine Foro K. Shakuntala |
| author_sort | B. Thimme Gowda |
| collection | DOAJ |
| description | In the title compound, Na+·C6H4BrClNO2S−·1.5H2O, one water molecule has crystallographically imposed twofold symmetry. The Na+ cation shows a pseudo-octahedral coordination provided by three O atoms of water molecules and three sulfonyl O atoms of different N-bromo-2-chlorobenzenesulfonamidate anions. The S—N distance of 1.579 (6) Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O—H...Br, O—H...N and O—H...O hydrogen bonds. |
| first_indexed | 2024-12-13T10:46:50Z |
| format | Article |
| id | doaj.art-b21fc90ada9749529689cb662d2ecfb8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:46:50Z |
| publishDate | 2011-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b21fc90ada9749529689cb662d2ecfb82022-12-21T23:50:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m870m87010.1107/S160053681102071XSodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrateB. Thimme GowdaSabine ForoK. ShakuntalaIn the title compound, Na+·C6H4BrClNO2S−·1.5H2O, one water molecule has crystallographically imposed twofold symmetry. The Na+ cation shows a pseudo-octahedral coordination provided by three O atoms of water molecules and three sulfonyl O atoms of different N-bromo-2-chlorobenzenesulfonamidate anions. The S—N distance of 1.579 (6) Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O—H...Br, O—H...N and O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S160053681102071X |
| spellingShingle | B. Thimme Gowda Sabine Foro K. Shakuntala Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate Acta Crystallographica Section E |
| title | Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate |
| title_full | Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate |
| title_fullStr | Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate |
| title_full_unstemmed | Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate |
| title_short | Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate |
| title_sort | sodium n bromo 2 chlorobenzenesulfonamidate sesquihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681102071X |
| work_keys_str_mv | AT bthimmegowda sodiumnbromo2chlorobenzenesulfonamidatesesquihydrate AT sabineforo sodiumnbromo2chlorobenzenesulfonamidatesesquihydrate AT kshakuntala sodiumnbromo2chlorobenzenesulfonamidatesesquihydrate |