Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A Review
Magnetic shape memory alloys (MSMAs) are an interesting class of smart materials characterized by undergoing macroscopic deformations upon the application of a pertinent stimulus: temperature, stress and/or external magnetic fields. Since the deformation is rapid and contactless, these materials are...
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2021-05-01
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author | Natalia A. Río-López Patricia Lázpita Daniel Salazar Viktor I. Petrenko Fernando Plazaola Volodymyr Chernenko Jose M. Porro |
author_facet | Natalia A. Río-López Patricia Lázpita Daniel Salazar Viktor I. Petrenko Fernando Plazaola Volodymyr Chernenko Jose M. Porro |
author_sort | Natalia A. Río-López |
collection | DOAJ |
description | Magnetic shape memory alloys (MSMAs) are an interesting class of smart materials characterized by undergoing macroscopic deformations upon the application of a pertinent stimulus: temperature, stress and/or external magnetic fields. Since the deformation is rapid and contactless, these materials are being extensively investigated for a plethora of applications, such as sensors and actuators for the medical, automotive and space industries, energy harvesting and damping devices, among others. These materials also exhibit a giant magnetocaloric effect, whereby they are very promising for magnetic refrigeration. The applications in which they can be used are extremely dependent on the material properties, which are, in turn, greatly conditioned by the structure, atomic ordering and magnetism of a material. Particularly, exploring the material structure is essential in order to push forward the current application limitations of the MSMAs. Among the wide range of available characterization tools, neutron scattering techniques stand out in acquiring advanced knowledge about the structure and magnetism of these alloys. Throughout this manuscript, a comprehensive review about the characterization of MSMAs using neutron techniques is presented. Several elastic neutron scattering techniques will be explained and exemplified, covering neutron imaging techniques—such as radiography, tomography and texture diffractometry; diffraction techniques—magnetic (polarized neutron) diffraction, powder neutron diffraction and single crystal neutron diffraction, reflectometry and small angle neutron scattering. This will be complemented with a few examples where inelastic neutron scattering has been employed to obtain information about the phonon dispersion in MSMAs. |
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language | English |
last_indexed | 2024-03-10T11:17:23Z |
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spelling | doaj.art-b222a243a3194d1aaab88e924ca81c982023-11-21T20:19:46ZengMDPI AGMetals2075-47012021-05-0111582910.3390/met11050829Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A ReviewNatalia A. Río-López0Patricia Lázpita1Daniel Salazar2Viktor I. Petrenko3Fernando Plazaola4Volodymyr Chernenko5Jose M. Porro6BCMaterials, Basque Center for Materials, Applications & Nanostructures, 48940 Leioa, SpainBCMaterials, Basque Center for Materials, Applications & Nanostructures, 48940 Leioa, SpainBCMaterials, Basque Center for Materials, Applications & Nanostructures, 48940 Leioa, SpainBCMaterials, Basque Center for Materials, Applications & Nanostructures, 48940 Leioa, SpainDepartment of Electricity and Electronics, Faculty of Science and Technology, University of the Basque Country, 48080 Bilbao, SpainBCMaterials, Basque Center for Materials, Applications & Nanostructures, 48940 Leioa, SpainBCMaterials, Basque Center for Materials, Applications & Nanostructures, 48940 Leioa, SpainMagnetic shape memory alloys (MSMAs) are an interesting class of smart materials characterized by undergoing macroscopic deformations upon the application of a pertinent stimulus: temperature, stress and/or external magnetic fields. Since the deformation is rapid and contactless, these materials are being extensively investigated for a plethora of applications, such as sensors and actuators for the medical, automotive and space industries, energy harvesting and damping devices, among others. These materials also exhibit a giant magnetocaloric effect, whereby they are very promising for magnetic refrigeration. The applications in which they can be used are extremely dependent on the material properties, which are, in turn, greatly conditioned by the structure, atomic ordering and magnetism of a material. Particularly, exploring the material structure is essential in order to push forward the current application limitations of the MSMAs. Among the wide range of available characterization tools, neutron scattering techniques stand out in acquiring advanced knowledge about the structure and magnetism of these alloys. Throughout this manuscript, a comprehensive review about the characterization of MSMAs using neutron techniques is presented. Several elastic neutron scattering techniques will be explained and exemplified, covering neutron imaging techniques—such as radiography, tomography and texture diffractometry; diffraction techniques—magnetic (polarized neutron) diffraction, powder neutron diffraction and single crystal neutron diffraction, reflectometry and small angle neutron scattering. This will be complemented with a few examples where inelastic neutron scattering has been employed to obtain information about the phonon dispersion in MSMAs.https://www.mdpi.com/2075-4701/11/5/829magnetic shape memory alloysneutron scatteringHeusler alloys |
spellingShingle | Natalia A. Río-López Patricia Lázpita Daniel Salazar Viktor I. Petrenko Fernando Plazaola Volodymyr Chernenko Jose M. Porro Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A Review Metals magnetic shape memory alloys neutron scattering Heusler alloys |
title | Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A Review |
title_full | Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A Review |
title_fullStr | Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A Review |
title_full_unstemmed | Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A Review |
title_short | Neutron Scattering as a Powerful Tool to Investigate Magnetic Shape Memory Alloys: A Review |
title_sort | neutron scattering as a powerful tool to investigate magnetic shape memory alloys a review |
topic | magnetic shape memory alloys neutron scattering Heusler alloys |
url | https://www.mdpi.com/2075-4701/11/5/829 |
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