Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrate
The cation of the complex title salt, [Zn(C13H11N3)2(H2O)](NO3)2, lies about a twofold rotation axis, which passes through the ZnII atom and the O atom of the aqua ligand. The ZnII atom adopts a distorted trigonal–bipyramidal geometry defined by two N atoms in axial positions [angle = 166.24 (7)°],...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015004636 |
| _version_ | 1818083788013436928 |
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| author | Yongtae Kim Sung Kwon Kang |
| author_facet | Yongtae Kim Sung Kwon Kang |
| author_sort | Yongtae Kim |
| collection | DOAJ |
| description | The cation of the complex title salt, [Zn(C13H11N3)2(H2O)](NO3)2, lies about a twofold rotation axis, which passes through the ZnII atom and the O atom of the aqua ligand. The ZnII atom adopts a distorted trigonal–bipyramidal geometry defined by two N atoms in axial positions [angle = 166.24 (7)°], and two N and one O atom in the equatorial plane [range of angles: 115.17 (7)–122.42 (3)°]. The dihedral angle between the imidazole and aniline rings is 23.86 (5)°. In the crystal, N—H...O and O—H...O hydrogen bonds link the components into a three-dimensional network. |
| first_indexed | 2024-12-10T19:43:33Z |
| format | Article |
| id | doaj.art-b227ecb06d7841f28ef0d97790ab71fe |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-10T19:43:33Z |
| publishDate | 2015-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-b227ecb06d7841f28ef0d97790ab71fe2022-12-22T01:35:56ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-04-01714m85m8610.1107/S2056989015004636tk5361Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrateYongtae Kim0Sung Kwon Kang1Department of Chemistry, Chungnam National University, Daejeon 305-764, Republic of KoreaDepartment of Chemistry, Chungnam National University, Daejeon 305-764, Republic of KoreaThe cation of the complex title salt, [Zn(C13H11N3)2(H2O)](NO3)2, lies about a twofold rotation axis, which passes through the ZnII atom and the O atom of the aqua ligand. The ZnII atom adopts a distorted trigonal–bipyramidal geometry defined by two N atoms in axial positions [angle = 166.24 (7)°], and two N and one O atom in the equatorial plane [range of angles: 115.17 (7)–122.42 (3)°]. The dihedral angle between the imidazole and aniline rings is 23.86 (5)°. In the crystal, N—H...O and O—H...O hydrogen bonds link the components into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989015004636crystal structurezinc complexbenzimidazolehydrogen bonding |
| spellingShingle | Yongtae Kim Sung Kwon Kang Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrate Acta Crystallographica Section E: Crystallographic Communications crystal structure zinc complex benzimidazole hydrogen bonding |
| title | Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrate |
| title_full | Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrate |
| title_fullStr | Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrate |
| title_full_unstemmed | Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrate |
| title_short | Crystal structure of aquabis[2-(1H-benzimidazol-2-yl-κN3)aniline-κN]zinc dinitrate |
| title_sort | crystal structure of aquabis 2 1h benzimidazol 2 yl κn3 aniline κn zinc dinitrate |
| topic | crystal structure zinc complex benzimidazole hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015004636 |
| work_keys_str_mv | AT yongtaekim crystalstructureofaquabis21hbenzimidazol2ylkn3anilineknzincdinitrate AT sungkwonkang crystalstructureofaquabis21hbenzimidazol2ylkn3anilineknzincdinitrate |