2-Amino-6-methylpyridinium 2-hydroxybenzoate
In the title molecular salt, C6H9N2+·C7H5O3−, the cation is protonated at its pyridine N atom and and makes a dihedral angle of 16.26 (9)° with the plane of the six-membered ring of the anion. The six-membered ring makes a dihedral angle of 6.09 (3)° with the attached carboxylate group. In the anion...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2016-05-01
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Series: | IUCrData |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616007471 |
Summary: | In the title molecular salt, C6H9N2+·C7H5O3−, the cation is protonated at its pyridine N atom and and makes a dihedral angle of 16.26 (9)° with the plane of the six-membered ring of the anion. The six-membered ring makes a dihedral angle of 6.09 (3)° with the attached carboxylate group. In the anion, an intramolecular O—H...O hydrogen bond generates an S(6) ring motif and a pair of N—H...O hydrogen bonds generates an R22(8) ring motif. In the crystal, the anions and cations are linked via N—H...O hydrogen bonds to form a tetramer. |
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ISSN: | 2414-3146 |