2-Amino-6-methylpyridinium 2-hydroxybenzoate
In the title molecular salt, C6H9N2+·C7H5O3−, the cation is protonated at its pyridine N atom and and makes a dihedral angle of 16.26 (9)° with the plane of the six-membered ring of the anion. The six-membered ring makes a dihedral angle of 6.09 (3)° with the attached carboxylate group. In the anion...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-05-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616007471 |
| _version_ | 1828822987324784640 |
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| author | P. Sivakumar S. Sudhahar S. Israel G. Chakkaravarthi |
| author_facet | P. Sivakumar S. Sudhahar S. Israel G. Chakkaravarthi |
| author_sort | P. Sivakumar |
| collection | DOAJ |
| description | In the title molecular salt, C6H9N2+·C7H5O3−, the cation is protonated at its pyridine N atom and and makes a dihedral angle of 16.26 (9)° with the plane of the six-membered ring of the anion. The six-membered ring makes a dihedral angle of 6.09 (3)° with the attached carboxylate group. In the anion, an intramolecular O—H...O hydrogen bond generates an S(6) ring motif and a pair of N—H...O hydrogen bonds generates an R22(8) ring motif. In the crystal, the anions and cations are linked via N—H...O hydrogen bonds to form a tetramer. |
| first_indexed | 2024-12-12T13:26:20Z |
| format | Article |
| id | doaj.art-b234bcb5b4414b849922af4e3d35c166 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-12T13:26:20Z |
| publishDate | 2016-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-b234bcb5b4414b849922af4e3d35c1662022-12-22T00:23:11ZengInternational Union of CrystallographyIUCrData2414-31462016-05-0115x16074710.1107/S2414314616007471bt40082-Amino-6-methylpyridinium 2-hydroxybenzoateP. Sivakumar0S. Sudhahar1S. Israel2G. Chakkaravarthi3Research and Development Centre, Bharathiar University, Coimbatore 641 046, IndiaDepartment of Physics, Alagappa University, Karaikkudi 630 003, IndiaDepartment of Physics, The American College, Madurai 625 002, IndiaDepartment of Physics, CPCL Polytechnic College, Chennai 600 068, IndiaIn the title molecular salt, C6H9N2+·C7H5O3−, the cation is protonated at its pyridine N atom and and makes a dihedral angle of 16.26 (9)° with the plane of the six-membered ring of the anion. The six-membered ring makes a dihedral angle of 6.09 (3)° with the attached carboxylate group. In the anion, an intramolecular O—H...O hydrogen bond generates an S(6) ring motif and a pair of N—H...O hydrogen bonds generates an R22(8) ring motif. In the crystal, the anions and cations are linked via N—H...O hydrogen bonds to form a tetramer.http://scripts.iucr.org/cgi-bin/paper?S2414314616007471crystal structuremolecular salthydrogen bonding |
| spellingShingle | P. Sivakumar S. Sudhahar S. Israel G. Chakkaravarthi 2-Amino-6-methylpyridinium 2-hydroxybenzoate IUCrData crystal structure molecular salt hydrogen bonding |
| title | 2-Amino-6-methylpyridinium 2-hydroxybenzoate |
| title_full | 2-Amino-6-methylpyridinium 2-hydroxybenzoate |
| title_fullStr | 2-Amino-6-methylpyridinium 2-hydroxybenzoate |
| title_full_unstemmed | 2-Amino-6-methylpyridinium 2-hydroxybenzoate |
| title_short | 2-Amino-6-methylpyridinium 2-hydroxybenzoate |
| title_sort | 2 amino 6 methylpyridinium 2 hydroxybenzoate |
| topic | crystal structure molecular salt hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616007471 |
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