Photoinduced transition-metal and external photosensitizer free phosphonation of unactivated C(sp2)–F bond via SET process under mild conditions

Photoinduced transition-metal and external photosensitizer free phosphonation of unactivated C(sp2)–F bond via SET process under mild conditions

Transition-metal catalyzed cross-couplings of aryl halides (ArI, ArBr and ArCl) with a broad range of nucleophiles have been developed as powerful methods for carbon–carbon and carbon–heteroatom bonds formation. However, due to the high bond dissociation energy of unactivated C(sp2)–F, cross-couplin...

Full description

Bibliographic Details
Main Authors: Qian Dou, Yatao Lang, Huiying Zeng, Chao-Jun Li
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-11-01
Series:Fundamental Research
Subjects:
Photochemistry
Catalyst-free
C–F bond cleavage
Phosphonation
Cross-coupling
Online Access:http://www.sciencedirect.com/science/article/pii/S2667325821001084

Internet

http://www.sciencedirect.com/science/article/pii/S2667325821001084

Similar Items