Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge Transport

Organic light‐emitting diodes (OLEDs) and organic solar cells are new members of trillion‐dollar semiconductor industry. The structure of these devices generally consists of a stack of several organic layers sandwiched between two electrodes. The electronic processes such as the energy‐level alignme...

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Main Authors: Peicheng Li, Zheng-Hong Lu
Format: Article
Language:English
Published: Wiley-VCH 2021-01-01
Series:Small Science
Subjects:
Online Access:https://doi.org/10.1002/smsc.202000015
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author Peicheng Li
Zheng-Hong Lu
author_facet Peicheng Li
Zheng-Hong Lu
author_sort Peicheng Li
collection DOAJ
description Organic light‐emitting diodes (OLEDs) and organic solar cells are new members of trillion‐dollar semiconductor industry. The structure of these devices generally consists of a stack of several organic layers sandwiched between two electrodes. The electronic processes such as the energy‐level alignment at and charge transport across these interfaces play a key role to the overall performance of the organic devices. Thus, interface physics is important for design and engineering of organic devices. Herein, recent progress in energy‐level alignment at and charge transport across organic interfaces is reviewed. In addition, basic material physics of organic semiconductors such as energy levels, energy disorder, and molecular orientation is introduced. Recent progress in theories and experiments on energy‐level alignment at and charge transport across molecular heterojunctions is then discussed. Case studies of applying interface physics for guiding fabrication of ideal devices are also provided.
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spelling doaj.art-b2574bb06ff8484599c0c4456570554a2022-12-21T19:13:25ZengWiley-VCHSmall Science2688-40462021-01-0111n/an/a10.1002/smsc.202000015Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge TransportPeicheng Li0Zheng-Hong Lu1Department of Materials Science and Engineering University of Toronto Toronto M5S 3E4 CanadaDepartment of Materials Science and Engineering University of Toronto Toronto M5S 3E4 CanadaOrganic light‐emitting diodes (OLEDs) and organic solar cells are new members of trillion‐dollar semiconductor industry. The structure of these devices generally consists of a stack of several organic layers sandwiched between two electrodes. The electronic processes such as the energy‐level alignment at and charge transport across these interfaces play a key role to the overall performance of the organic devices. Thus, interface physics is important for design and engineering of organic devices. Herein, recent progress in energy‐level alignment at and charge transport across organic interfaces is reviewed. In addition, basic material physics of organic semiconductors such as energy levels, energy disorder, and molecular orientation is introduced. Recent progress in theories and experiments on energy‐level alignment at and charge transport across molecular heterojunctions is then discussed. Case studies of applying interface physics for guiding fabrication of ideal devices are also provided.https://doi.org/10.1002/smsc.202000015charge transportelectronic propertiesenergy-level alignmentorganic interfacesorganic optoelectronics
spellingShingle Peicheng Li
Zheng-Hong Lu
Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge Transport
Small Science
charge transport
electronic properties
energy-level alignment
organic interfaces
organic optoelectronics
title Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge Transport
title_full Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge Transport
title_fullStr Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge Transport
title_full_unstemmed Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge Transport
title_short Interface Engineering in Organic Electronics: Energy‐Level Alignment and Charge Transport
title_sort interface engineering in organic electronics energy level alignment and charge transport
topic charge transport
electronic properties
energy-level alignment
organic interfaces
organic optoelectronics
url https://doi.org/10.1002/smsc.202000015
work_keys_str_mv AT peichengli interfaceengineeringinorganicelectronicsenergylevelalignmentandchargetransport
AT zhenghonglu interfaceengineeringinorganicelectronicsenergylevelalignmentandchargetransport