Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction Parameters
Abstract Two different shaped Ni‐based metal–organic framework (MOF) nanosheets are prepared from hexagonal nickel hydroxide monolayer nanosheets under the variable reaction conditions. The hexagonal shaped MOF with similar lateral size to Ni(OH)2 nanosheet is obtained on flat Si substrate but the t...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2023-08-01
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| Series: | Advanced Materials Interfaces |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/admi.202300335 |
| _version_ | 1797742986862264320 |
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| author | Agamoni Pathak Kazuto Hatakeyama Shintaro Ida |
| author_facet | Agamoni Pathak Kazuto Hatakeyama Shintaro Ida |
| author_sort | Agamoni Pathak |
| collection | DOAJ |
| description | Abstract Two different shaped Ni‐based metal–organic framework (MOF) nanosheets are prepared from hexagonal nickel hydroxide monolayer nanosheets under the variable reaction conditions. The hexagonal shaped MOF with similar lateral size to Ni(OH)2 nanosheet is obtained on flat Si substrate but the thickness increased from 1 to 2 nm. Another rectangular MOF nanosheet is obtained when a similar reaction is carried out in a solution in which Ni(OH)2 is dispersed. The difference in the shape of the Ni‐MOF nanosheets is related to the degree of dissolution of the Ni(OH)2 nanosheets during the reaction. |
| first_indexed | 2024-03-12T14:48:06Z |
| format | Article |
| id | doaj.art-b2830aa0066b4a7d89a63f0b854f05ee |
| institution | Directory Open Access Journal |
| issn | 2196-7350 |
| language | English |
| last_indexed | 2024-03-12T14:48:06Z |
| publishDate | 2023-08-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Advanced Materials Interfaces |
| spelling | doaj.art-b2830aa0066b4a7d89a63f0b854f05ee2023-08-16T01:35:27ZengWiley-VCHAdvanced Materials Interfaces2196-73502023-08-011023n/an/a10.1002/admi.202300335Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction ParametersAgamoni Pathak0Kazuto Hatakeyama1Shintaro Ida2Graduate School of Science and Technology Kumamoto University 2‐39‐1 Kurokami Chuo‐ku Kumamoto 860–8555 JapanGraduate School of Science and Technology Institute of Industrial Nanomaterials (IINA) Kumamoto University 2‐39‐1 Kurokami Chuo‐ku Kumamoto 860–8555 JapanGraduate School of Science and Technology Institute of Industrial Nanomaterials (IINA) Kumamoto University 2‐39‐1 Kurokami Chuo‐ku Kumamoto 860–8555 JapanAbstract Two different shaped Ni‐based metal–organic framework (MOF) nanosheets are prepared from hexagonal nickel hydroxide monolayer nanosheets under the variable reaction conditions. The hexagonal shaped MOF with similar lateral size to Ni(OH)2 nanosheet is obtained on flat Si substrate but the thickness increased from 1 to 2 nm. Another rectangular MOF nanosheet is obtained when a similar reaction is carried out in a solution in which Ni(OH)2 is dispersed. The difference in the shape of the Ni‐MOF nanosheets is related to the degree of dissolution of the Ni(OH)2 nanosheets during the reaction.https://doi.org/10.1002/admi.2023003352D‐nanosheetfree standing ultrathin filmsmetal hydroxidemetal–organic frameworksmorphology controlproton conduction |
| spellingShingle | Agamoni Pathak Kazuto Hatakeyama Shintaro Ida Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction Parameters Advanced Materials Interfaces 2D‐nanosheet free standing ultrathin films metal hydroxide metal–organic frameworks morphology control proton conduction |
| title | Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction Parameters |
| title_full | Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction Parameters |
| title_fullStr | Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction Parameters |
| title_full_unstemmed | Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction Parameters |
| title_short | Morphology Control of Two dimensional (2D) Metal–Organic Framework Nanosheets via 1 nm Thick Hexagonal Hydroxide Nanosheets through Variable Reaction Parameters |
| title_sort | morphology control of two dimensional 2d metal organic framework nanosheets via 1 nm thick hexagonal hydroxide nanosheets through variable reaction parameters |
| topic | 2D‐nanosheet free standing ultrathin films metal hydroxide metal–organic frameworks morphology control proton conduction |
| url | https://doi.org/10.1002/admi.202300335 |
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