Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions

Abstract This work demonstrates the design and straightforward syntheses of several novel probe-based on rhodamine B and 2-mercaptoquinoline-3-carbaldehydes as a naked-eye colorimetric probe, indicating a sensitive and selective recognition towards nickel (II) with a limit of detection 0.30 μmol L−1...

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Main Authors: Seyyed Emad Hooshmand, Behnaz Baeiszadeh, Masoumeh Mohammadnejad, Razieh Ghasemi, Farshad Darvishi, Ali Khatibi, Morteza Shiri, Faiq H. S. Hussain
Format: Article
Language:English
Published: Nature Portfolio 2023-10-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-023-44395-x
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author Seyyed Emad Hooshmand
Behnaz Baeiszadeh
Masoumeh Mohammadnejad
Razieh Ghasemi
Farshad Darvishi
Ali Khatibi
Morteza Shiri
Faiq H. S. Hussain
author_facet Seyyed Emad Hooshmand
Behnaz Baeiszadeh
Masoumeh Mohammadnejad
Razieh Ghasemi
Farshad Darvishi
Ali Khatibi
Morteza Shiri
Faiq H. S. Hussain
author_sort Seyyed Emad Hooshmand
collection DOAJ
description Abstract This work demonstrates the design and straightforward syntheses of several novel probe-based on rhodamine B and 2-mercaptoquinoline-3-carbaldehydes as a naked-eye colorimetric probe, indicating a sensitive and selective recognition towards nickel (II) with a limit of detection 0.30 μmol L−1 (0.02 mg L−1). Further, by employing the oxidation property of hypochlorite (OCl−), this novel probe parallelly has been deployed to detect hypochlorite in laboratory conditions with a limit of detection of 0.19 μmol mL−1 and in living cells. Regarded to negligible cell toxicity toward mammalian cells, this probe has the potential to determine these analytes in in-vivo investigation and foodstuff samples.
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spelling doaj.art-b288057a50104fe7898641e7d8eaded72023-11-19T13:09:24ZengNature PortfolioScientific Reports2045-23222023-10-011311910.1038/s41598-023-44395-xNovel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ionsSeyyed Emad Hooshmand0Behnaz Baeiszadeh1Masoumeh Mohammadnejad2Razieh Ghasemi3Farshad Darvishi4Ali Khatibi5Morteza Shiri6Faiq H. S. Hussain7Department of Organic Chemistry, Faculty of Chemistry, Alzahra UniversityDepartment of Organic Chemistry, Faculty of Chemistry, Alzahra UniversityDepartment of Analytical Chemistry, Faculty of Chemistry, Alzahra UniversityDepartment of Nanotechnology, Jabir Ibn Hayyan Institute, Technical and Vocational Training OrganizationDepartment of Microbiology, Faculty of Biological Sciences, Alzahra UniversityDepartment of Biotechnology, Faculty of Biological Sciences, Alzahra UniversityDepartment of Organic Chemistry, Faculty of Chemistry, Alzahra UniversityDepartment of Medical Analysis, Faculty of Applied Science, Tishk International University-ErbilAbstract This work demonstrates the design and straightforward syntheses of several novel probe-based on rhodamine B and 2-mercaptoquinoline-3-carbaldehydes as a naked-eye colorimetric probe, indicating a sensitive and selective recognition towards nickel (II) with a limit of detection 0.30 μmol L−1 (0.02 mg L−1). Further, by employing the oxidation property of hypochlorite (OCl−), this novel probe parallelly has been deployed to detect hypochlorite in laboratory conditions with a limit of detection of 0.19 μmol mL−1 and in living cells. Regarded to negligible cell toxicity toward mammalian cells, this probe has the potential to determine these analytes in in-vivo investigation and foodstuff samples.https://doi.org/10.1038/s41598-023-44395-x
spellingShingle Seyyed Emad Hooshmand
Behnaz Baeiszadeh
Masoumeh Mohammadnejad
Razieh Ghasemi
Farshad Darvishi
Ali Khatibi
Morteza Shiri
Faiq H. S. Hussain
Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions
Scientific Reports
title Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions
title_full Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions
title_fullStr Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions
title_full_unstemmed Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions
title_short Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions
title_sort novel probe based on rhodamine b and quinoline as a naked eye colorimetric probe for dual detection of nickel and hypochlorite ions
url https://doi.org/10.1038/s41598-023-44395-x
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