Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate
The title compound, H3O+·C4H10NO6P2−·H2O, was obtained from the reaction of cyclopropanecarbonitrile with PCl3, followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808037094 |
| Summary: | The title compound, H3O+·C4H10NO6P2−·H2O, was obtained from the reaction of cyclopropanecarbonitrile with PCl3, followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phosphonic acid residues and a water molecule of crystallization. The hydroxonium cation and water molecule are hydrogen bonded to the anion and further N—H...O and O—H...O bonds create a three-dimensional network. |
|---|---|
| ISSN: | 1600-5368 |