Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate
The title compound, H3O+·C4H10NO6P2−·H2O, was obtained from the reaction of cyclopropanecarbonitrile with PCl3, followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808037094 |
| _version_ | 1798018410026631168 |
|---|---|
| author | V. I. Pekhnyo A. N. Kozachkova A. V. Dudko V. V. Bon |
| author_facet | V. I. Pekhnyo A. N. Kozachkova A. V. Dudko V. V. Bon |
| author_sort | V. I. Pekhnyo |
| collection | DOAJ |
| description | The title compound, H3O+·C4H10NO6P2−·H2O, was obtained from the reaction of cyclopropanecarbonitrile with PCl3, followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phosphonic acid residues and a water molecule of crystallization. The hydroxonium cation and water molecule are hydrogen bonded to the anion and further N—H...O and O—H...O bonds create a three-dimensional network. |
| first_indexed | 2024-04-11T16:23:41Z |
| format | Article |
| id | doaj.art-b29ec1aaf7ea4630874fa048d41e0924 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:23:41Z |
| publishDate | 2008-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b29ec1aaf7ea4630874fa048d41e09242022-12-22T04:14:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412o2344o234410.1107/S1600536808037094Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrateV. I. PekhnyoA. N. KozachkovaA. V. DudkoV. V. BonThe title compound, H3O+·C4H10NO6P2−·H2O, was obtained from the reaction of cyclopropanecarbonitrile with PCl3, followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phosphonic acid residues and a water molecule of crystallization. The hydroxonium cation and water molecule are hydrogen bonded to the anion and further N—H...O and O—H...O bonds create a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808037094 |
| spellingShingle | V. I. Pekhnyo A. N. Kozachkova A. V. Dudko V. V. Bon Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate Acta Crystallographica Section E |
| title | Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate |
| title_full | Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate |
| title_fullStr | Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate |
| title_full_unstemmed | Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate |
| title_short | Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate |
| title_sort | oxonium ammonio cyclopropyl methylenebis hydrogenphosphonate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808037094 |
| work_keys_str_mv | AT vipekhnyo oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate AT ankozachkova oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate AT avdudko oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate AT vvbon oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate |