Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff bases
A series of octahedral Ru(III), Rh(III) and Ir(III) complexes have been prepared with tetradentate Schiff bases derived by condensing isatin with 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,2-diaminobenzene and 1,3-diaminobenzene. The obtained complexes were characterized on the basi...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Serbian Chemical Society
2006-01-01
|
| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390609917S.pdf |
| _version_ | 1824014800966909952 |
|---|---|
| author | Sharma V.K. Srivastava Ankita Srivastava Shipra |
| author_facet | Sharma V.K. Srivastava Ankita Srivastava Shipra |
| author_sort | Sharma V.K. |
| collection | DOAJ |
| description | A series of octahedral Ru(III), Rh(III) and Ir(III) complexes have been prepared with tetradentate Schiff bases derived by condensing isatin with 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,2-diaminobenzene and 1,3-diaminobenzene. The obtained complexes were characterized on the basis of their elemental analyses, magnetic moment, conductance, IR electronic, 1HNMR and FAB mass spectra, as well as thermal analyses. The Ru(III) complexes are low spin paramagnetic, while Rh(III) and Ir(III) behave as diamagnetic complexes. The IR spectral data revealed that all the Schiff bases behave as tetradentate and are coordinated to Ru(III), Rh(III) and Ir(III) via nitrogen and oxygen. Antifungal studies of the ligands as well as their complexes were carried out by the agar plate method. |
| first_indexed | 2024-12-18T22:19:27Z |
| format | Article |
| id | doaj.art-b29f5d27115f42cc88943097baebb639 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-18T22:19:27Z |
| publishDate | 2006-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-b29f5d27115f42cc88943097baebb6392022-12-21T20:49:44ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212006-01-01718-991792810.2298/JSC0609917S0352-51390609917SSynthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff basesSharma V.K.0Srivastava Ankita1Srivastava Shipra2Department of Chemistry, University of Lucknow, LucknowDepartment of Chemistry, University of Lucknow, LucknowDepartment of Chemistry, University of Lucknow, LucknowA series of octahedral Ru(III), Rh(III) and Ir(III) complexes have been prepared with tetradentate Schiff bases derived by condensing isatin with 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,2-diaminobenzene and 1,3-diaminobenzene. The obtained complexes were characterized on the basis of their elemental analyses, magnetic moment, conductance, IR electronic, 1HNMR and FAB mass spectra, as well as thermal analyses. The Ru(III) complexes are low spin paramagnetic, while Rh(III) and Ir(III) behave as diamagnetic complexes. The IR spectral data revealed that all the Schiff bases behave as tetradentate and are coordinated to Ru(III), Rh(III) and Ir(III) via nitrogen and oxygen. Antifungal studies of the ligands as well as their complexes were carried out by the agar plate method.http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390609917S.pdfru(iii)rh(iii)ir(iii)complexesschiff basespectral and antifungalstudies |
| spellingShingle | Sharma V.K. Srivastava Ankita Srivastava Shipra Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff bases Journal of the Serbian Chemical Society ru(iii) rh(iii) ir(iii) complexes schiff base spectral and antifungalstudies |
| title | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff bases |
| title_full | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff bases |
| title_fullStr | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff bases |
| title_full_unstemmed | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff bases |
| title_short | Synthetic, structural and antifungal studies of coordination compounds of Ru(III), Rh(III) and Ir(III) with tetradentate schiff bases |
| title_sort | synthetic structural and antifungal studies of coordination compounds of ru iii rh iii and ir iii with tetradentate schiff bases |
| topic | ru(iii) rh(iii) ir(iii) complexes schiff base spectral and antifungalstudies |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390609917S.pdf |
| work_keys_str_mv | AT sharmavk syntheticstructuralandantifungalstudiesofcoordinationcompoundsofruiiirhiiiandiriiiwithtetradentateschiffbases AT srivastavaankita syntheticstructuralandantifungalstudiesofcoordinationcompoundsofruiiirhiiiandiriiiwithtetradentateschiffbases AT srivastavashipra syntheticstructuralandantifungalstudiesofcoordinationcompoundsofruiiirhiiiandiriiiwithtetradentateschiffbases |