| Summary: | Consumers’ appreciation of wines is mainly driven by their aroma, which is the most important organoleptic characteristic and key attribute. The volatile bouquet derives from the grape berries and from the processing phases of vinification. In the present study, the volatile emission of six grapevine cultivars has been analysed through four phases of vinification: the headspaces of crushed grapes, fermented must, new wine (2 months old), and wine (7 months old) have been sampled and analysed. This showed the evolution of the volatile compounds based on the chemical and mechanical processes involved in the specific vinification phase. Chemometric tools (hierarchical cluster and principal component analyses) have revealed that samples gather in statistical groups based on the vinification phase they belong to, though they maintain an aroma composition that is typical of the grape berry of origin.
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