Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)]
In the title compound, {[Zn(C9H9N5)2(H2O)2](ClO4)2}n, the ZnII ion lies on an inversion center and is coordinated by two triazolyl N atoms and two pyridyl N atoms from four symmetry-related N-1-(3-pyridyl)ethylidene-4H-1,2,4-triazol-4-amine (L) ligands and two O atoms from coordinated water molecule...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809013130 |
| _version_ | 1819281188518363136 |
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| author | Qiaozhen Sun Donghua Miao Wei Wang Xianhua He Xiaodan Sun |
| author_facet | Qiaozhen Sun Donghua Miao Wei Wang Xianhua He Xiaodan Sun |
| author_sort | Qiaozhen Sun |
| collection | DOAJ |
| description | In the title compound, {[Zn(C9H9N5)2(H2O)2](ClO4)2}n, the ZnII ion lies on an inversion center and is coordinated by two triazolyl N atoms and two pyridyl N atoms from four symmetry-related N-1-(3-pyridyl)ethylidene-4H-1,2,4-triazol-4-amine (L) ligands and two O atoms from coordinated water molecules in a slightly distorted octahedral environment. Each L ligand bridges symmetry-related ZnII ions, forming a two-dimensional layer with a (4,4) grid. In the crystal structure, intermolecular O—H...O hydrogen bonds connect perchlorate counter-anions to the layers. |
| first_indexed | 2024-12-24T00:55:43Z |
| format | Article |
| id | doaj.art-b2c193981d324e5abf8c01b4b8955636 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:55:43Z |
| publishDate | 2009-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b2c193981d324e5abf8c01b4b89556362022-12-21T17:23:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m518m51910.1107/S1600536809013130Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)]Qiaozhen SunDonghua MiaoWei WangXianhua HeXiaodan SunIn the title compound, {[Zn(C9H9N5)2(H2O)2](ClO4)2}n, the ZnII ion lies on an inversion center and is coordinated by two triazolyl N atoms and two pyridyl N atoms from four symmetry-related N-1-(3-pyridyl)ethylidene-4H-1,2,4-triazol-4-amine (L) ligands and two O atoms from coordinated water molecules in a slightly distorted octahedral environment. Each L ligand bridges symmetry-related ZnII ions, forming a two-dimensional layer with a (4,4) grid. In the crystal structure, intermolecular O—H...O hydrogen bonds connect perchlorate counter-anions to the layers.http://scripts.iucr.org/cgi-bin/paper?S1600536809013130 |
| spellingShingle | Qiaozhen Sun Donghua Miao Wei Wang Xianhua He Xiaodan Sun Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)] Acta Crystallographica Section E |
| title | Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)] |
| title_full | Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)] |
| title_fullStr | Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)] |
| title_full_unstemmed | Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)] |
| title_short | Poly[[diaqua{N-[1-(3-pyridyl)ethylidene]-4H-1,2,4-triazol-4-amine}zinc(II)] bis(perchlorate)] |
| title_sort | poly diaqua n 1 3 pyridyl ethylidene 4h 1 2 4 triazol 4 amine zinc ii bis perchlorate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809013130 |
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