Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study
Mimicking the biological olfaction, large odor-sensor arrays can be used to acquire a broad range of chemical information, with a potentially high degree of redundancy, to allow for enhanced control over the sensitivity and selectivity of artificial olfaction systems. The arrays should consist of th...
Main Authors: | , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2017-07-01
|
Series: | Sensors |
Subjects: | |
Online Access: | https://www.mdpi.com/1424-8220/17/7/1606 |
_version_ | 1828354102242836480 |
---|---|
author | Bartosz Wyszynski Rui Yatabe Atsuo Nakao Masaya Nakatani Akio Oki Hiroaki Oka Kiyoshi Toko |
author_facet | Bartosz Wyszynski Rui Yatabe Atsuo Nakao Masaya Nakatani Akio Oki Hiroaki Oka Kiyoshi Toko |
author_sort | Bartosz Wyszynski |
collection | DOAJ |
description | Mimicking the biological olfaction, large odor-sensor arrays can be used to acquire a broad range of chemical information, with a potentially high degree of redundancy, to allow for enhanced control over the sensitivity and selectivity of artificial olfaction systems. The arrays should consist of the largest possible number of individual sensing elements while being miniaturized. Chemosensitive resistors are one of the sensing platforms that have a potential to satisfy these two conditions. In this work we test viability of fabricating a 16-element chemosensitive resistor array for detection and recognition of volatile organic compounds (VOCs). The sensors were fabricated using blends of carbon black and gas chromatography (GC) stationary-phase materials preselected based on their sorption properties. Blends of the selected GC materials with carbon black particles were subsequently coated over chemosensitive resistor devices and the resulting sensors/arrays evaluated in exposure experiments against vapors of pyrrole, benzenal, nonanal, and 2-phenethylamine at 150, 300, 450, and 900 ppb. Responses of the fabricated 16-element array were stable and differed for each individual odorant sample, proving the blends of GC materials with carbon black particles can be effectively used for fabrication of large odor-sensing arrays based on chemosensitive resistors. The obtained results suggest that the proposed sensing devices could be effective in discriminating odor/vapor samples at the sub-ppm level. |
first_indexed | 2024-04-14T02:18:56Z |
format | Article |
id | doaj.art-b2df80c3453e4e17af92018864e57016 |
institution | Directory Open Access Journal |
issn | 1424-8220 |
language | English |
last_indexed | 2024-04-14T02:18:56Z |
publishDate | 2017-07-01 |
publisher | MDPI AG |
record_format | Article |
series | Sensors |
spelling | doaj.art-b2df80c3453e4e17af92018864e570162022-12-22T02:18:06ZengMDPI AGSensors1424-82202017-07-01177160610.3390/s17071606s17071606Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic StudyBartosz Wyszynski0Rui Yatabe1Atsuo Nakao2Masaya Nakatani3Akio Oki4Hiroaki Oka5Kiyoshi Toko6Research and Development Center for Taste and Odor Sensing, Nishi-ku, Motooka 744, Fukuoka 819-0395, JapanResearch and Development Center for Taste and Odor Sensing, Nishi-ku, Motooka 744, Fukuoka 819-0395, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanResearch and Development Center for Taste and Odor Sensing, Nishi-ku, Motooka 744, Fukuoka 819-0395, JapanMimicking the biological olfaction, large odor-sensor arrays can be used to acquire a broad range of chemical information, with a potentially high degree of redundancy, to allow for enhanced control over the sensitivity and selectivity of artificial olfaction systems. The arrays should consist of the largest possible number of individual sensing elements while being miniaturized. Chemosensitive resistors are one of the sensing platforms that have a potential to satisfy these two conditions. In this work we test viability of fabricating a 16-element chemosensitive resistor array for detection and recognition of volatile organic compounds (VOCs). The sensors were fabricated using blends of carbon black and gas chromatography (GC) stationary-phase materials preselected based on their sorption properties. Blends of the selected GC materials with carbon black particles were subsequently coated over chemosensitive resistor devices and the resulting sensors/arrays evaluated in exposure experiments against vapors of pyrrole, benzenal, nonanal, and 2-phenethylamine at 150, 300, 450, and 900 ppb. Responses of the fabricated 16-element array were stable and differed for each individual odorant sample, proving the blends of GC materials with carbon black particles can be effectively used for fabrication of large odor-sensing arrays based on chemosensitive resistors. The obtained results suggest that the proposed sensing devices could be effective in discriminating odor/vapor samples at the sub-ppm level.https://www.mdpi.com/1424-8220/17/7/1606odor sensorchemical sensorartificial olfactionchemoresistancesensor arrayGC materialcarbon black |
spellingShingle | Bartosz Wyszynski Rui Yatabe Atsuo Nakao Masaya Nakatani Akio Oki Hiroaki Oka Kiyoshi Toko Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study Sensors odor sensor chemical sensor artificial olfaction chemoresistance sensor array GC material carbon black |
title | Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study |
title_full | Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study |
title_fullStr | Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study |
title_full_unstemmed | Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study |
title_short | Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study |
title_sort | array of chemosensitive resistors with composites of gas chromatography gc materials and carbon black for detection and recognition of vocs a basic study |
topic | odor sensor chemical sensor artificial olfaction chemoresistance sensor array GC material carbon black |
url | https://www.mdpi.com/1424-8220/17/7/1606 |
work_keys_str_mv | AT bartoszwyszynski arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy AT ruiyatabe arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy AT atsuonakao arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy AT masayanakatani arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy AT akiooki arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy AT hiroakioka arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy AT kiyoshitoko arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy |