Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study

Mimicking the biological olfaction, large odor-sensor arrays can be used to acquire a broad range of chemical information, with a potentially high degree of redundancy, to allow for enhanced control over the sensitivity and selectivity of artificial olfaction systems. The arrays should consist of th...

Full description

Bibliographic Details
Main Authors: Bartosz Wyszynski, Rui Yatabe, Atsuo Nakao, Masaya Nakatani, Akio Oki, Hiroaki Oka, Kiyoshi Toko
Format: Article
Language:English
Published: MDPI AG 2017-07-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/17/7/1606
_version_ 1828354102242836480
author Bartosz Wyszynski
Rui Yatabe
Atsuo Nakao
Masaya Nakatani
Akio Oki
Hiroaki Oka
Kiyoshi Toko
author_facet Bartosz Wyszynski
Rui Yatabe
Atsuo Nakao
Masaya Nakatani
Akio Oki
Hiroaki Oka
Kiyoshi Toko
author_sort Bartosz Wyszynski
collection DOAJ
description Mimicking the biological olfaction, large odor-sensor arrays can be used to acquire a broad range of chemical information, with a potentially high degree of redundancy, to allow for enhanced control over the sensitivity and selectivity of artificial olfaction systems. The arrays should consist of the largest possible number of individual sensing elements while being miniaturized. Chemosensitive resistors are one of the sensing platforms that have a potential to satisfy these two conditions. In this work we test viability of fabricating a 16-element chemosensitive resistor array for detection and recognition of volatile organic compounds (VOCs). The sensors were fabricated using blends of carbon black and gas chromatography (GC) stationary-phase materials preselected based on their sorption properties. Blends of the selected GC materials with carbon black particles were subsequently coated over chemosensitive resistor devices and the resulting sensors/arrays evaluated in exposure experiments against vapors of pyrrole, benzenal, nonanal, and 2-phenethylamine at 150, 300, 450, and 900 ppb. Responses of the fabricated 16-element array were stable and differed for each individual odorant sample, proving the blends of GC materials with carbon black particles can be effectively used for fabrication of large odor-sensing arrays based on chemosensitive resistors. The obtained results suggest that the proposed sensing devices could be effective in discriminating odor/vapor samples at the sub-ppm level.
first_indexed 2024-04-14T02:18:56Z
format Article
id doaj.art-b2df80c3453e4e17af92018864e57016
institution Directory Open Access Journal
issn 1424-8220
language English
last_indexed 2024-04-14T02:18:56Z
publishDate 2017-07-01
publisher MDPI AG
record_format Article
series Sensors
spelling doaj.art-b2df80c3453e4e17af92018864e570162022-12-22T02:18:06ZengMDPI AGSensors1424-82202017-07-01177160610.3390/s17071606s17071606Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic StudyBartosz Wyszynski0Rui Yatabe1Atsuo Nakao2Masaya Nakatani3Akio Oki4Hiroaki Oka5Kiyoshi Toko6Research and Development Center for Taste and Odor Sensing, Nishi-ku, Motooka 744, Fukuoka 819-0395, JapanResearch and Development Center for Taste and Odor Sensing, Nishi-ku, Motooka 744, Fukuoka 819-0395, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanPanasonic Automotive & Industrial Systems Company, Sensing Solutions Development Center, Kadomoa-shi, Oaza Kadoma 1006, Osaka 571-8501, JapanResearch and Development Center for Taste and Odor Sensing, Nishi-ku, Motooka 744, Fukuoka 819-0395, JapanMimicking the biological olfaction, large odor-sensor arrays can be used to acquire a broad range of chemical information, with a potentially high degree of redundancy, to allow for enhanced control over the sensitivity and selectivity of artificial olfaction systems. The arrays should consist of the largest possible number of individual sensing elements while being miniaturized. Chemosensitive resistors are one of the sensing platforms that have a potential to satisfy these two conditions. In this work we test viability of fabricating a 16-element chemosensitive resistor array for detection and recognition of volatile organic compounds (VOCs). The sensors were fabricated using blends of carbon black and gas chromatography (GC) stationary-phase materials preselected based on their sorption properties. Blends of the selected GC materials with carbon black particles were subsequently coated over chemosensitive resistor devices and the resulting sensors/arrays evaluated in exposure experiments against vapors of pyrrole, benzenal, nonanal, and 2-phenethylamine at 150, 300, 450, and 900 ppb. Responses of the fabricated 16-element array were stable and differed for each individual odorant sample, proving the blends of GC materials with carbon black particles can be effectively used for fabrication of large odor-sensing arrays based on chemosensitive resistors. The obtained results suggest that the proposed sensing devices could be effective in discriminating odor/vapor samples at the sub-ppm level.https://www.mdpi.com/1424-8220/17/7/1606odor sensorchemical sensorartificial olfactionchemoresistancesensor arrayGC materialcarbon black
spellingShingle Bartosz Wyszynski
Rui Yatabe
Atsuo Nakao
Masaya Nakatani
Akio Oki
Hiroaki Oka
Kiyoshi Toko
Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study
Sensors
odor sensor
chemical sensor
artificial olfaction
chemoresistance
sensor array
GC material
carbon black
title Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study
title_full Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study
title_fullStr Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study
title_full_unstemmed Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study
title_short Array of Chemosensitive Resistors with Composites of Gas Chromatography (GC) Materials and Carbon Black for Detection and Recognition of VOCs: A Basic Study
title_sort array of chemosensitive resistors with composites of gas chromatography gc materials and carbon black for detection and recognition of vocs a basic study
topic odor sensor
chemical sensor
artificial olfaction
chemoresistance
sensor array
GC material
carbon black
url https://www.mdpi.com/1424-8220/17/7/1606
work_keys_str_mv AT bartoszwyszynski arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy
AT ruiyatabe arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy
AT atsuonakao arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy
AT masayanakatani arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy
AT akiooki arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy
AT hiroakioka arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy
AT kiyoshitoko arrayofchemosensitiveresistorswithcompositesofgaschromatographygcmaterialsandcarbonblackfordetectionandrecognitionofvocsabasicstudy