(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
The title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative. The crystal structure of the racemic (R,R/S,S) modification reveals two near-orthogonal five-membered heterocyclic ring systems, each in an e...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2019-04-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619005200 |
| _version_ | 1828972499480608768 |
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| author | Craig M. Forsyth Zohreh Nazarian |
| author_facet | Craig M. Forsyth Zohreh Nazarian |
| author_sort | Craig M. Forsyth |
| collection | DOAJ |
| description | The title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative. The crystal structure of the racemic (R,R/S,S) modification reveals two near-orthogonal five-membered heterocyclic ring systems, each in an envelope configuration. |
| first_indexed | 2024-12-14T13:29:05Z |
| format | Article |
| id | doaj.art-b2ebf11225ef49f48bbc26055432d889 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-14T13:29:05Z |
| publishDate | 2019-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-b2ebf11225ef49f48bbc26055432d8892022-12-21T22:59:45ZengInternational Union of CrystallographyIUCrData2414-31462019-04-0144x19052010.1107/S2414314619005200nk4001(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dioneCraig M. Forsyth0Zohreh Nazarian1School of Chemistry, Monash University, Clayton 3800, AustraliaSchool of Chemistry, Monash University, Clayton 3800, AustraliaThe title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative. The crystal structure of the racemic (R,R/S,S) modification reveals two near-orthogonal five-membered heterocyclic ring systems, each in an envelope configuration.http://scripts.iucr.org/cgi-bin/paper?S2414314619005200crystal structurespirocyclic compoundscyclization reactionsoxazolidinone |
| spellingShingle | Craig M. Forsyth Zohreh Nazarian (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione IUCrData crystal structure spirocyclic compounds cyclization reactions oxazolidinone |
| title | (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione |
| title_full | (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione |
| title_fullStr | (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione |
| title_full_unstemmed | (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione |
| title_short | (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione |
| title_sort | r r s s 9 benzyl 3 methyl 7 phenyl 1 6 dioxa 3 9 diazaspiro 4 4 nonane 2 8 dione |
| topic | crystal structure spirocyclic compounds cyclization reactions oxazolidinone |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619005200 |
| work_keys_str_mv | AT craigmforsyth rrss9benzyl3methyl7phenyl16dioxa39diazaspiro44nonane28dione AT zohrehnazarian rrss9benzyl3methyl7phenyl16dioxa39diazaspiro44nonane28dione |