Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate
In the title compound, [Cu(SO4)(C15H11N5)(H2O)]·CH3OH·2H2O, the CuII ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812014134 |
| _version_ | 1819291323779252224 |
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| author | Liang Yuan Liu Shu Lian Chi Yan Hui Zhao Yan Xia Shi Jing Min |
| author_facet | Liang Yuan Liu Shu Lian Chi Yan Hui Zhao Yan Xia Shi Jing Min |
| author_sort | Liang Yuan |
| collection | DOAJ |
| description | In the title compound, [Cu(SO4)(C15H11N5)(H2O)]·CH3OH·2H2O, the CuII ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water molecule is located at the apex. In the crystal, hydrogen-bonding interactions involving the coordinating and solvent water molecules, the methanol solvent molecule and the amine group (one with an intramolecular interaction to one of the sulfate O atoms) of the complex are observed. π–π interactions between symmetry-related phenantroline moieties, with a shortest centroid–centroid interaction of 3.573 (2)°, are also present. |
| first_indexed | 2024-12-24T03:36:49Z |
| format | Article |
| id | doaj.art-b30a359c3c0a42888cdddc2214dd42fb |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:36:49Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b30a359c3c0a42888cdddc2214dd42fb2022-12-21T17:17:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m558m55910.1107/S1600536812014134Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrateLiang YuanLiu Shu LianChi Yan HuiZhao Yan XiaShi Jing MinIn the title compound, [Cu(SO4)(C15H11N5)(H2O)]·CH3OH·2H2O, the CuII ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water molecule is located at the apex. In the crystal, hydrogen-bonding interactions involving the coordinating and solvent water molecules, the methanol solvent molecule and the amine group (one with an intramolecular interaction to one of the sulfate O atoms) of the complex are observed. π–π interactions between symmetry-related phenantroline moieties, with a shortest centroid–centroid interaction of 3.573 (2)°, are also present.http://scripts.iucr.org/cgi-bin/paper?S1600536812014134 |
| spellingShingle | Liang Yuan Liu Shu Lian Chi Yan Hui Zhao Yan Xia Shi Jing Min Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate Acta Crystallographica Section E |
| title | Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate |
| title_full | Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate |
| title_fullStr | Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate |
| title_full_unstemmed | Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate |
| title_short | Aqua[1-(1,10-phenanthrolin-2-yl-κ2N,N′)-1H-pyrazol-3-amine-κN2](sulfato-κO)copper(II) methanol monosolvate dihydrate |
| title_sort | aqua 1 1 10 phenanthrolin 2 yl amp 954 2n n amp 8242 1h pyrazol 3 amine amp 954 n2 sulfato amp 954 o copper ii methanol monosolvate dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812014134 |
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