[Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV)
The title compound, [SnCl4(C10H8N2Se)], was obtained by the reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The SnIV ion is coordinated by two N atoms [Sn—N = 2.266 (2) and 2.274 (2) Å] from the bis(2-py...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681202586X |
| _version_ | 1828143570325864448 |
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| author | Gunay Z. Mammadova Zhanna V. Matsulevich Vladimir K. Osmanov Alexander V. Borisov Victor N. Khrustalev |
| author_facet | Gunay Z. Mammadova Zhanna V. Matsulevich Vladimir K. Osmanov Alexander V. Borisov Victor N. Khrustalev |
| author_sort | Gunay Z. Mammadova |
| collection | DOAJ |
| description | The title compound, [SnCl4(C10H8N2Se)], was obtained by the reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The SnIV ion is coordinated by two N atoms [Sn—N = 2.266 (2) and 2.274 (2) Å] from the bis(2-pyridyl)selenide ligand and four chloride anions [Sn—Cl = 2.3717 (6)–2.3939 (6) Å] in a distorted octahedral geometry. The central six-membered chelate ring has a boat conformation with the Se and Sn atoms deviating by 0.692 (3) and 0.855 (3) Å, respectively, from the mean plane through the remaining four ring atoms. The pyridine rings are inclined to each other by a dihedral angle of 49.62 (8)°. The crystal packing exhibits short intermolecular Se...Cl contacts [3.5417 (7) and 3.5648 (7) Å], weak C—H...Cl hydrogen bonds and π–π stacking interactions between the pyridine rings with a centroid–centroid distance of 3.683 (3) Å. |
| first_indexed | 2024-04-11T19:59:25Z |
| format | Article |
| id | doaj.art-b32f78ea7cbf411e8c03241672b6f5bf |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:59:25Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b32f78ea7cbf411e8c03241672b6f5bf2022-12-22T04:05:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m983m98310.1107/S160053681202586X[Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV)Gunay Z. MammadovaZhanna V. MatsulevichVladimir K. OsmanovAlexander V. BorisovVictor N. KhrustalevThe title compound, [SnCl4(C10H8N2Se)], was obtained by the reaction of 2,2′-dipyridyl diselenide with tin tetrachloride. The SnIV ion is coordinated by two N atoms [Sn—N = 2.266 (2) and 2.274 (2) Å] from the bis(2-pyridyl)selenide ligand and four chloride anions [Sn—Cl = 2.3717 (6)–2.3939 (6) Å] in a distorted octahedral geometry. The central six-membered chelate ring has a boat conformation with the Se and Sn atoms deviating by 0.692 (3) and 0.855 (3) Å, respectively, from the mean plane through the remaining four ring atoms. The pyridine rings are inclined to each other by a dihedral angle of 49.62 (8)°. The crystal packing exhibits short intermolecular Se...Cl contacts [3.5417 (7) and 3.5648 (7) Å], weak C—H...Cl hydrogen bonds and π–π stacking interactions between the pyridine rings with a centroid–centroid distance of 3.683 (3) Å.http://scripts.iucr.org/cgi-bin/paper?S160053681202586X |
| spellingShingle | Gunay Z. Mammadova Zhanna V. Matsulevich Vladimir K. Osmanov Alexander V. Borisov Victor N. Khrustalev [Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV) Acta Crystallographica Section E |
| title | [Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV) |
| title_full | [Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV) |
| title_fullStr | [Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV) |
| title_full_unstemmed | [Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV) |
| title_short | [Bis(pyridin-2-yl) selenide-κ2N,N′]tetrachloridotin(IV) |
| title_sort | bis pyridin 2 yl selenide amp 954 2n n amp 8242 tetrachloridotin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681202586X |
| work_keys_str_mv | AT gunayzmammadova bispyridin2ylselenideamp9542nnamp8242tetrachloridotiniv AT zhannavmatsulevich bispyridin2ylselenideamp9542nnamp8242tetrachloridotiniv AT vladimirkosmanov bispyridin2ylselenideamp9542nnamp8242tetrachloridotiniv AT alexandervborisov bispyridin2ylselenideamp9542nnamp8242tetrachloridotiniv AT victornkhrustalev bispyridin2ylselenideamp9542nnamp8242tetrachloridotiniv |