| Summary: | Mild catalytic oxidation of thioethers and thiophenes is an important reaction for the synthesis of molecules with pharmaceutical interest, as well as for the development of efficient processes able to remove sulfur-containing pollutants from fuels and wastewater. With respect to the green chemistry principles, hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) is the ideal oxidant and the Me-containing porous materials (Me = Ti, V, Mo, W, Zr) are among the best heterogeneous catalysts for these applications. The main classes of catalysts, including Me-microporous and mesoporous silicates, Me-layered double hydroxides, Me-metal–organic frameworks, are described in this review. The catalytic active species generated in the presence of H<sub>2</sub>O<sub>2</sub>, as well as the probable oxidation mechanisms, are also addressed. The reactivity of molecules in the sulfoxidation process and the role played by the solvents are explored.
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