High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteries

Tin dioxide (SnO2) with multiple electron transport is considered as a potential substitute for graphite due to these advantages of natural abundance, environmental friendliness, and high theoretical capacity. However, the ineluctable volume change and structural crushing limit its practical applica...

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Main Authors: Wanming Teng, Zhenbao Lu, Xuelei Li, Xiaohu wang, Jun Liu, Junhui Dong, Ding Nan
Format: Article
Language:English
Published: Elsevier 2022-08-01
Series:Electrochemistry Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1388248122001473
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author Wanming Teng
Zhenbao Lu
Xuelei Li
Xiaohu wang
Jun Liu
Junhui Dong
Ding Nan
author_facet Wanming Teng
Zhenbao Lu
Xuelei Li
Xiaohu wang
Jun Liu
Junhui Dong
Ding Nan
author_sort Wanming Teng
collection DOAJ
description Tin dioxide (SnO2) with multiple electron transport is considered as a potential substitute for graphite due to these advantages of natural abundance, environmental friendliness, and high theoretical capacity. However, the ineluctable volume change and structural crushing limit its practical application. Hence, SnO2 is coated by an N-doped graphite layer to form the flexible composite anode (SnO2@NG), which can provide a conductive network, increase the electronic conductivity, and effectively mitigate the irreversible volume expansion/contraction during the circulation process. Furthermore, the SnO2@NG anode shows a high specific capacity and stable cycle performance in lithium-ion batteries (677.7 mAh g−1 after 100 cycles) and sodium-ion batteries (169.7 mAh g−1 after 100 cycles). This excellent electrochemical performance illustrates that SnO2@NG has broad application prospects for high-performance energy storage systems.
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spelling doaj.art-b341b215ad2e467591e382d55db986c92022-12-22T04:26:35ZengElsevierElectrochemistry Communications1388-24812022-08-01141107345High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteriesWanming Teng0Zhenbao Lu1Xuelei Li2Xiaohu wang3Jun Liu4Junhui Dong5Ding Nan6College of Chemistry and Chemical Engineering, Inner Mongolia University, West University Street 235, Hohhot, 010021, China; Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot, 010051, ChinaInner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot, 010051, ChinaInner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot, 010051, ChinaInner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot, 010051, China; Rising Graphite Applied Technology Research Institute, Chinese Graphite Industrial Park-Xinghe, Ulanqab, Inner Mongolia, 013650, ChinaInner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot, 010051, China; Corresponding authors.Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot, 010051, ChinaCollege of Chemistry and Chemical Engineering, Inner Mongolia University, West University Street 235, Hohhot, 010021, China; Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot, 010051, China; Corresponding authors.Tin dioxide (SnO2) with multiple electron transport is considered as a potential substitute for graphite due to these advantages of natural abundance, environmental friendliness, and high theoretical capacity. However, the ineluctable volume change and structural crushing limit its practical application. Hence, SnO2 is coated by an N-doped graphite layer to form the flexible composite anode (SnO2@NG), which can provide a conductive network, increase the electronic conductivity, and effectively mitigate the irreversible volume expansion/contraction during the circulation process. Furthermore, the SnO2@NG anode shows a high specific capacity and stable cycle performance in lithium-ion batteries (677.7 mAh g−1 after 100 cycles) and sodium-ion batteries (169.7 mAh g−1 after 100 cycles). This excellent electrochemical performance illustrates that SnO2@NG has broad application prospects for high-performance energy storage systems.http://www.sciencedirect.com/science/article/pii/S1388248122001473Lithium-ion batteriesSodium-ion batteriesSnO2N-doped graphite layerExcellent electrochemical performance
spellingShingle Wanming Teng
Zhenbao Lu
Xuelei Li
Xiaohu wang
Jun Liu
Junhui Dong
Ding Nan
High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteries
Electrochemistry Communications
Lithium-ion batteries
Sodium-ion batteries
SnO2
N-doped graphite layer
Excellent electrochemical performance
title High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteries
title_full High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteries
title_fullStr High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteries
title_full_unstemmed High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteries
title_short High-performance flexible SnO2 anode boosted by an N-doped graphite coating layer for lithium-ion and sodium-ion batteries
title_sort high performance flexible sno2 anode boosted by an n doped graphite coating layer for lithium ion and sodium ion batteries
topic Lithium-ion batteries
Sodium-ion batteries
SnO2
N-doped graphite layer
Excellent electrochemical performance
url http://www.sciencedirect.com/science/article/pii/S1388248122001473
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