Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of State

The shape of the working fluid’s temperature-entropy saturation boundary has a strong influence, not only on the process parameters and efficiency of the Organic Rankine Cycle, but also on the design (the layout) of the equipment. In this paper, working fluids are modelled by the Redlich-Kwong equat...

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Main Authors: Axel Groniewsky, Attila R. Imre
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Entropy
Subjects:
Online Access:http://www.mdpi.com/1099-4300/20/2/93
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author Axel Groniewsky
Attila R. Imre
author_facet Axel Groniewsky
Attila R. Imre
author_sort Axel Groniewsky
collection DOAJ
description The shape of the working fluid’s temperature-entropy saturation boundary has a strong influence, not only on the process parameters and efficiency of the Organic Rankine Cycle, but also on the design (the layout) of the equipment. In this paper, working fluids are modelled by the Redlich-Kwong equation of state. It is demonstrated that a limiting isochoric heat capacity might exist between dry and wet fluids. With the Redlich-Kwong equation of state, this limit can be predicted with good accuracy for several fluids, including alkanes.
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spelling doaj.art-b3502e57230340b6a634a07d39c675b42022-12-22T01:56:38ZengMDPI AGEntropy1099-43002018-01-012029310.3390/e20020093e20020093Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of StateAxel Groniewsky0Attila R. Imre1Department of Energy Engineering, Budapest University of Technology and Economics, Muegyetem rkp. 3, H-1111 Budapest, HungaryDepartment of Energy Engineering, Budapest University of Technology and Economics, Muegyetem rkp. 3, H-1111 Budapest, HungaryThe shape of the working fluid’s temperature-entropy saturation boundary has a strong influence, not only on the process parameters and efficiency of the Organic Rankine Cycle, but also on the design (the layout) of the equipment. In this paper, working fluids are modelled by the Redlich-Kwong equation of state. It is demonstrated that a limiting isochoric heat capacity might exist between dry and wet fluids. With the Redlich-Kwong equation of state, this limit can be predicted with good accuracy for several fluids, including alkanes.http://www.mdpi.com/1099-4300/20/2/93Organic Rankine Cycleisochoric heat capacityvibrational degree of freedom
spellingShingle Axel Groniewsky
Attila R. Imre
Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of State
Entropy
Organic Rankine Cycle
isochoric heat capacity
vibrational degree of freedom
title Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of State
title_full Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of State
title_fullStr Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of State
title_full_unstemmed Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of State
title_short Prediction of the ORC Working Fluid’s Temperature-Entropy Saturation Boundary Using Redlich-Kwong Equation of State
title_sort prediction of the orc working fluid s temperature entropy saturation boundary using redlich kwong equation of state
topic Organic Rankine Cycle
isochoric heat capacity
vibrational degree of freedom
url http://www.mdpi.com/1099-4300/20/2/93
work_keys_str_mv AT axelgroniewsky predictionoftheorcworkingfluidstemperatureentropysaturationboundaryusingredlichkwongequationofstate
AT attilarimre predictionoftheorcworkingfluidstemperatureentropysaturationboundaryusingredlichkwongequationofstate