Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface Water

Nowadays, ammonia nitrogen (NH<sub>4</sub><sup>+</sup>) pollution gets more and more attention in drinking water sources. This study investigated the main behavior of biogeochemical NH<sub>4</sub><sup>+</sup> from groundwater to surface water in a hypo...

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Main Authors: Ailan Yan, Xianyan Guo, Donghui Hu, Xiaoyang Chen
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/14/8/1237
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author Ailan Yan
Xianyan Guo
Donghui Hu
Xiaoyang Chen
author_facet Ailan Yan
Xianyan Guo
Donghui Hu
Xiaoyang Chen
author_sort Ailan Yan
collection DOAJ
description Nowadays, ammonia nitrogen (NH<sub>4</sub><sup>+</sup>) pollution gets more and more attention in drinking water sources. This study investigated the main behavior of biogeochemical NH<sub>4</sub><sup>+</sup> from groundwater to surface water in a hyporheic zone (HZ) sediment from a reservoir. The experiments were conducted using synthetic groundwater to investigate ammonium transformation. The results indicated that ammonium concentration decreased, apparently resulting from the influence of microbial oxidation and ion exchange with Ca<sup>2+</sup>, Mg<sup>2+</sup>, K<sup>+</sup>, and Na<sup>+</sup>. However, all the ammonium in the sediment was oxidized, then the adsorbed NH<sub>4</sub><sup>+</sup> became bioavailable by being released back when NH<sub>4</sub><sup>+</sup> concentration decreased in the aqueous phase. The results showed NH<sub>4</sub><sup>+</sup> behavior in a HZ where the aerobic and anaerobic environments frequently exchange, with different hydrological conditions controlled by a strong coupling between microbial activities, geochemistry, hydrology, and ion exchange.
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spelling doaj.art-b36a145f6b5f4007ad3b19554a4629872023-12-03T14:05:10ZengMDPI AGWater2073-44412022-04-01148123710.3390/w14081237Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface WaterAilan Yan0Xianyan Guo1Donghui Hu2Xiaoyang Chen3Key Laboratory for Technology in Rural Water Management of Zhejiang Province, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, ChinaProduction & Technology Department, Reconnaissance and Design Institute, Qiantang River Administration of Zhejiang Province, Hangzhou 310018, ChinaHydraulic and Agriculture Engineering Department, Yuyao Water Conservancy Bureau, Yuyao 315402, ChinaKey Laboratory for Technology in Rural Water Management of Zhejiang Province, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, ChinaNowadays, ammonia nitrogen (NH<sub>4</sub><sup>+</sup>) pollution gets more and more attention in drinking water sources. This study investigated the main behavior of biogeochemical NH<sub>4</sub><sup>+</sup> from groundwater to surface water in a hyporheic zone (HZ) sediment from a reservoir. The experiments were conducted using synthetic groundwater to investigate ammonium transformation. The results indicated that ammonium concentration decreased, apparently resulting from the influence of microbial oxidation and ion exchange with Ca<sup>2+</sup>, Mg<sup>2+</sup>, K<sup>+</sup>, and Na<sup>+</sup>. However, all the ammonium in the sediment was oxidized, then the adsorbed NH<sub>4</sub><sup>+</sup> became bioavailable by being released back when NH<sub>4</sub><sup>+</sup> concentration decreased in the aqueous phase. The results showed NH<sub>4</sub><sup>+</sup> behavior in a HZ where the aerobic and anaerobic environments frequently exchange, with different hydrological conditions controlled by a strong coupling between microbial activities, geochemistry, hydrology, and ion exchange.https://www.mdpi.com/2073-4441/14/8/1237hyporheic zoneammonium (NH<sub>4</sub><sup>+</sup>) pollutionbiological oxidationion exchange
spellingShingle Ailan Yan
Xianyan Guo
Donghui Hu
Xiaoyang Chen
Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface Water
Water
hyporheic zone
ammonium (NH<sub>4</sub><sup>+</sup>) pollution
biological oxidation
ion exchange
title Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface Water
title_full Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface Water
title_fullStr Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface Water
title_full_unstemmed Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface Water
title_short Reactive Transport of NH<sub>4</sub><sup>+</sup> in the Hyporheic Zone from the Ground Water to the Surface Water
title_sort reactive transport of nh sub 4 sub sup sup in the hyporheic zone from the ground water to the surface water
topic hyporheic zone
ammonium (NH<sub>4</sub><sup>+</sup>) pollution
biological oxidation
ion exchange
url https://www.mdpi.com/2073-4441/14/8/1237
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AT donghuihu reactivetransportofnhsub4subsupsupinthehyporheiczonefromthegroundwatertothesurfacewater
AT xiaoyangchen reactivetransportofnhsub4subsupsupinthehyporheiczonefromthegroundwatertothesurfacewater