Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication
A series of new hexasubstituted cyclotriphosphaze derivatives containing Schiff base linkages were successfully synthesized and characterized. The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spec...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-09-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/14/18/3768 |
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| author | Nurul Atiqah Mohd Taip Zuhair Jamain Ismawati Palle |
| author_facet | Nurul Atiqah Mohd Taip Zuhair Jamain Ismawati Palle |
| author_sort | Nurul Atiqah Mohd Taip |
| collection | DOAJ |
| description | A series of new hexasubstituted cyclotriphosphaze derivatives containing Schiff base linkages were successfully synthesized and characterized. The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and carbon, hydrogen, and nitrogen (CHN) elemental analysis were used to characterize the intermediates and final compounds, while the thermal stability of the final compounds is evaluated with a thermogravimetric analysis (TGA) test. The final compounds are physically added to the polyurethane coating formulation and then applied to the wood panel using a brush and the compound’s fire-retardant properties are evaluated using the limiting oxygen index (LOI) test. In this research, compound <b>3b</b> showed good thermal stability compared to compound <b>3a</b>. In terms of LOI results, polyurethane with an LOI value of 21.90% was employed as a matrix for wood coating and the value increased to 24.90% when this polyurethane is incorporated with 1 wt.% of the compound <b>3b</b>. The increase in the LOI value indicates that the wood coating containing hexasubstituted cyclotriphosphazene compounds exhibits excellent fire-retardant properties as additives. |
| first_indexed | 2024-03-09T22:45:46Z |
| format | Article |
| id | doaj.art-b37414eb646b4887be4bf52f967863cd |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-09T22:45:46Z |
| publishDate | 2022-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-b37414eb646b4887be4bf52f967863cd2023-11-23T18:29:34ZengMDPI AGPolymers2073-43602022-09-011418376810.3390/polym14183768Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood FabricationNurul Atiqah Mohd Taip0Zuhair Jamain1Ismawati Palle2Organic Synthesis and Advanced Materials (OSAM) Research Group, Faculty of Science and Natural Resources, Universiti Malaysia Sabah (UMS), Kota Kinabalu 88400, Sabah, MalaysiaOrganic Synthesis and Advanced Materials (OSAM) Research Group, Faculty of Science and Natural Resources, Universiti Malaysia Sabah (UMS), Kota Kinabalu 88400, Sabah, MalaysiaFaculty of Tropical Forestry, Universiti Malaysia Sabah (UMS), Kota Kinabalu 88400, Sabah, MalaysiaA series of new hexasubstituted cyclotriphosphaze derivatives containing Schiff base linkages were successfully synthesized and characterized. The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and carbon, hydrogen, and nitrogen (CHN) elemental analysis were used to characterize the intermediates and final compounds, while the thermal stability of the final compounds is evaluated with a thermogravimetric analysis (TGA) test. The final compounds are physically added to the polyurethane coating formulation and then applied to the wood panel using a brush and the compound’s fire-retardant properties are evaluated using the limiting oxygen index (LOI) test. In this research, compound <b>3b</b> showed good thermal stability compared to compound <b>3a</b>. In terms of LOI results, polyurethane with an LOI value of 21.90% was employed as a matrix for wood coating and the value increased to 24.90% when this polyurethane is incorporated with 1 wt.% of the compound <b>3b</b>. The increase in the LOI value indicates that the wood coating containing hexasubstituted cyclotriphosphazene compounds exhibits excellent fire-retardant properties as additives.https://www.mdpi.com/2073-4360/14/18/3768cyclotriphosphazeneSchiff basewood coatingfire-retardant |
| spellingShingle | Nurul Atiqah Mohd Taip Zuhair Jamain Ismawati Palle Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication Polymers cyclotriphosphazene Schiff base wood coating fire-retardant |
| title | Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication |
| title_full | Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication |
| title_fullStr | Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication |
| title_full_unstemmed | Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication |
| title_short | Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication |
| title_sort | fire retardant property of hexasubstituted cyclotriphosphazene derivatives with schiff base linking unit applied as an additives in polyurethane coating for wood fabrication |
| topic | cyclotriphosphazene Schiff base wood coating fire-retardant |
| url | https://www.mdpi.com/2073-4360/14/18/3768 |
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