X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine
The new 1D-coordination polymer of CuII ion, {(2- apymH)2[Cu(pyzdc)2] .6H2O}n, (2-apym = 2-aminopyrimidine, pyzdcH2 = 1,4- pyrazine-2,3-dicarboxylic acid), was synthesized based on proton transfer mechanism and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2012-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100153M.pdf |
| _version_ | 1811311429497651200 |
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| author | Mirzaei Masoud Eshtiagh-Hosseini Hossein Hassanpoor Azam Barba Victor |
| author_facet | Mirzaei Masoud Eshtiagh-Hosseini Hossein Hassanpoor Azam Barba Victor |
| author_sort | Mirzaei Masoud |
| collection | DOAJ |
| description | The new 1D-coordination polymer of CuII ion, {(2- apymH)2[Cu(pyzdc)2] .6H2O}n, (2-apym = 2-aminopyrimidine, pyzdcH2 = 1,4- pyrazine-2,3-dicarboxylic acid), was synthesized based on proton transfer mechanism and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. The coordination polymer consists of infinite anionic chains of [Cu(pyzdc)2]2- anion bridged crossing double chain running along a-axis and discrete (2-apymH)+ fragment. The CuII ion is located on inversion centre in the basal plane of an elongated octahedron and two oxygen atoms from adjacent (pyzdc)2-ligands occupy axial position. The interaction between oxygen atoms of water molecules along with the dicarboxylic acid play an important role in the overall supramolecular assembly. |
| first_indexed | 2024-04-13T10:18:50Z |
| format | Article |
| id | doaj.art-b38d155c181a4b2e9b926394fd34b31e |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-04-13T10:18:50Z |
| publishDate | 2012-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-b38d155c181a4b2e9b926394fd34b31e2022-12-22T02:50:38ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392012-01-01771677310.2298/JSC101115153MX-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidineMirzaei MasoudEshtiagh-Hosseini HosseinHassanpoor AzamBarba VictorThe new 1D-coordination polymer of CuII ion, {(2- apymH)2[Cu(pyzdc)2] .6H2O}n, (2-apym = 2-aminopyrimidine, pyzdcH2 = 1,4- pyrazine-2,3-dicarboxylic acid), was synthesized based on proton transfer mechanism and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. The coordination polymer consists of infinite anionic chains of [Cu(pyzdc)2]2- anion bridged crossing double chain running along a-axis and discrete (2-apymH)+ fragment. The CuII ion is located on inversion centre in the basal plane of an elongated octahedron and two oxygen atoms from adjacent (pyzdc)2-ligands occupy axial position. The interaction between oxygen atoms of water molecules along with the dicarboxylic acid play an important role in the overall supramolecular assembly.http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100153M.pdfcopper1,4-pyrazine-2,3-dicarboxylic acid2-aminopyrimidineproton transferhydrogen bondcoordination polymerwater cluster |
| spellingShingle | Mirzaei Masoud Eshtiagh-Hosseini Hossein Hassanpoor Azam Barba Victor X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine Journal of the Serbian Chemical Society copper 1,4-pyrazine-2,3-dicarboxylic acid 2-aminopyrimidine proton transfer hydrogen bond coordination polymer water cluster |
| title | X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine |
| title_full | X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine |
| title_fullStr | X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine |
| title_full_unstemmed | X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine |
| title_short | X-ray structure of 1D-coordination polymer of copperII bearing 1,4-pyrazine-2,3-dicarboxylic acid and 2-aminopyrimidine |
| title_sort | x ray structure of 1d coordination polymer of copperii bearing 1 4 pyrazine 2 3 dicarboxylic acid and 2 aminopyrimidine |
| topic | copper 1,4-pyrazine-2,3-dicarboxylic acid 2-aminopyrimidine proton transfer hydrogen bond coordination polymer water cluster |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100153M.pdf |
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