Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence properties
Three new metal coordination polymers with different spatial structure, namely {[Co2(H2O)6(4-PDCA)2]2·3H2O}n (SNUT-12), {[Cd(H2O)2(4-PDCA)]·2H2O}n (SNUT-13) and [Zn2(4-PDCA)2]n (SNUT-14), where H2(4-PDCA) = 1-(4-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylic acid, were synthesized...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-12-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535223007761 |
| _version_ | 1797615944354234368 |
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| author | Jia-Hao Gao Pei-Pei Huang Jie Liu Nan Zheng Dong Wang Si-Yu Yue Er-Nu Liu Quan Liu Bo Liu Jiu-Fu Lu |
| author_facet | Jia-Hao Gao Pei-Pei Huang Jie Liu Nan Zheng Dong Wang Si-Yu Yue Er-Nu Liu Quan Liu Bo Liu Jiu-Fu Lu |
| author_sort | Jia-Hao Gao |
| collection | DOAJ |
| description | Three new metal coordination polymers with different spatial structure, namely {[Co2(H2O)6(4-PDCA)2]2·3H2O}n (SNUT-12), {[Cd(H2O)2(4-PDCA)]·2H2O}n (SNUT-13) and [Zn2(4-PDCA)2]n (SNUT-14), where H2(4-PDCA) = 1-(4-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylic acid, were synthesized by changing the central ion with the same ligand under solvothermal and hydrothermal conditions, which were further characterized by single crystal X-ray diffraction, powder XRD, FT-IR and TGA. Single crystal X-ray analysis revealed that SNUT-12 exhibits a 1D infinite zigzag chains which were constructed by Cobalt(II) ion and 4-PDCA2− ligand, SNUT-13 features a 2D ladder-like structure. Meanwhile, SNUT-14 displays 2-fold 3D → 3D parallel interpenetrating frameworks. In addition, SNUT-12 exhibited high electrocatalytic oxygen evolution reaction, and SNUT-13, SNUT-14 showed strong fluorescence at room temperature. |
| first_indexed | 2024-03-11T07:34:10Z |
| format | Article |
| id | doaj.art-b3ad9fa146ea4cc797ab53ac83ec1e1e |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-03-11T07:34:10Z |
| publishDate | 2023-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-b3ad9fa146ea4cc797ab53ac83ec1e1e2023-11-17T05:25:58ZengElsevierArabian Journal of Chemistry1878-53522023-12-011612105314Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence propertiesJia-Hao Gao0Pei-Pei Huang1Jie Liu2Nan Zheng3Dong Wang4Si-Yu Yue5Er-Nu Liu6Quan Liu7Bo Liu8Jiu-Fu Lu9Shaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR China; Medical Research and Experiment Center, Shaanxi University of Chinese Medicine, Xianyang 712000, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR ChinaShaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR China; Corresponding authors.Shaanxi Province Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, PR China; Corresponding authors.Three new metal coordination polymers with different spatial structure, namely {[Co2(H2O)6(4-PDCA)2]2·3H2O}n (SNUT-12), {[Cd(H2O)2(4-PDCA)]·2H2O}n (SNUT-13) and [Zn2(4-PDCA)2]n (SNUT-14), where H2(4-PDCA) = 1-(4-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylic acid, were synthesized by changing the central ion with the same ligand under solvothermal and hydrothermal conditions, which were further characterized by single crystal X-ray diffraction, powder XRD, FT-IR and TGA. Single crystal X-ray analysis revealed that SNUT-12 exhibits a 1D infinite zigzag chains which were constructed by Cobalt(II) ion and 4-PDCA2− ligand, SNUT-13 features a 2D ladder-like structure. Meanwhile, SNUT-14 displays 2-fold 3D → 3D parallel interpenetrating frameworks. In addition, SNUT-12 exhibited high electrocatalytic oxygen evolution reaction, and SNUT-13, SNUT-14 showed strong fluorescence at room temperature.http://www.sciencedirect.com/science/article/pii/S1878535223007761Coordination polymersSpatial structureElectrocatalysisPhotoluminescence properties |
| spellingShingle | Jia-Hao Gao Pei-Pei Huang Jie Liu Nan Zheng Dong Wang Si-Yu Yue Er-Nu Liu Quan Liu Bo Liu Jiu-Fu Lu Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence properties Arabian Journal of Chemistry Coordination polymers Spatial structure Electrocatalysis Photoluminescence properties |
| title | Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence properties |
| title_full | Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence properties |
| title_fullStr | Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence properties |
| title_full_unstemmed | Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence properties |
| title_short | Construction of three novel Co/Zn/Cd(II) coordination polymers based on the same ligands: Different spatial structures, electrocatalysis and photoluminescence properties |
| title_sort | construction of three novel co zn cd ii coordination polymers based on the same ligands different spatial structures electrocatalysis and photoluminescence properties |
| topic | Coordination polymers Spatial structure Electrocatalysis Photoluminescence properties |
| url | http://www.sciencedirect.com/science/article/pii/S1878535223007761 |
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