trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate
The title compound, trans-[RhCl(C18H12Cl3P)2(CO)]·C3H6O, contains an Rh(I) atom in a distorted square-planar coordination with a P—Rh—P angle of 175.27 (2)° and Rh—P bond lengths of 2.3127 (4) and 2.3219&...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810039814 |
| _version_ | 1818945715767869440 |
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| author | Andrew R. Burgoyne Reinout Meijboom Alfred Muller Bernard O. Omondi |
| author_facet | Andrew R. Burgoyne Reinout Meijboom Alfred Muller Bernard O. Omondi |
| author_sort | Andrew R. Burgoyne |
| collection | DOAJ |
| description | The title compound, trans-[RhCl(C18H12Cl3P)2(CO)]·C3H6O, contains an Rh(I) atom in a distorted square-planar coordination with a P—Rh—P angle of 175.27 (2)° and Rh—P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak intermolecular contacts between the acetone methyl groups and the carbonyl O atom. Interactions between the acetone solvent molecule and the Cl—Rh unit results in a reduced P—Rh—Cl angle of 86.675 (15)°. |
| first_indexed | 2024-12-20T08:03:32Z |
| format | Article |
| id | doaj.art-b3c8010280a24ccd9aec34ef3a340861 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:03:32Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b3c8010280a24ccd9aec34ef3a3408612022-12-21T19:47:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1380m138110.1107/S1600536810039814trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvateAndrew R. BurgoyneReinout MeijboomAlfred MullerBernard O. OmondiThe title compound, trans-[RhCl(C18H12Cl3P)2(CO)]·C3H6O, contains an Rh(I) atom in a distorted square-planar coordination with a P—Rh—P angle of 175.27 (2)° and Rh—P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak intermolecular contacts between the acetone methyl groups and the carbonyl O atom. Interactions between the acetone solvent molecule and the Cl—Rh unit results in a reduced P—Rh—Cl angle of 86.675 (15)°.http://scripts.iucr.org/cgi-bin/paper?S1600536810039814 |
| spellingShingle | Andrew R. Burgoyne Reinout Meijboom Alfred Muller Bernard O. Omondi trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate Acta Crystallographica Section E |
| title | trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate |
| title_full | trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate |
| title_fullStr | trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate |
| title_full_unstemmed | trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate |
| title_short | trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate |
| title_sort | trans carbonylchloridobis tris 4 chlorophenyl phosphane rhodium i acetone monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810039814 |
| work_keys_str_mv | AT andrewrburgoyne transcarbonylchloridobistris4chlorophenylphosphanerhodiumiacetonemonosolvate AT reinoutmeijboom transcarbonylchloridobistris4chlorophenylphosphanerhodiumiacetonemonosolvate AT alfredmuller transcarbonylchloridobistris4chlorophenylphosphanerhodiumiacetonemonosolvate AT bernardoomondi transcarbonylchloridobistris4chlorophenylphosphanerhodiumiacetonemonosolvate |