Nitrous Oxide Adsorption and Decomposition on Zeolites and Zeolite-like Materials
Decomposition of N<sub>2</sub>O on modified zeolites, crystalline titanosilicalites, and related amorphous systems is studied by the catalytic and spectroscopic methods. Zinc-containing HZSM-5 zeolites and titanosilicalites with moderate Ti/Si ratios are shown to exhibit a better catalyt...
| Main Authors: | , , |
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| Format: | Article |
| Jezik: | English |
| Izdano: |
MDPI AG
2022-01-01
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| Serija: | Molecules |
| Teme: | |
| Online dostop: | https://www.mdpi.com/1420-3049/27/2/398 |
| Izvleček: | Decomposition of N<sub>2</sub>O on modified zeolites, crystalline titanosilicalites, and related amorphous systems is studied by the catalytic and spectroscopic methods. Zinc-containing HZSM-5 zeolites and titanosilicalites with moderate Ti/Si ratios are shown to exhibit a better catalytic performance in N<sub>2</sub>O decomposition as compared with conventionally used Cu/HZSM-5 zeolites and amorphous Cu-containing catalysts. Dehydroxylation of the HZSM-5 zeolite by calcination at 1120 K results in an enhancement of the N<sub>2</sub>O conversion. The mechanism of the reaction and the role of coordinatively unsaturated cations and Lewis acid sites in N<sub>2</sub>O decomposition are discussed on the basis of the spectroscopic data. |
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| ISSN: | 1420-3049 |