Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions
The magadiite–magnetite (MAG–Fe<sub>3</sub>O<sub>4</sub>) nanocomposite has great potential applications in the field of biomaterials research. It has been used as a novel magnetic sorbent, prepared by co-precipitation method. It has the dual advantage of...
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2019-04-01
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author | Mingliang Ge Zhuangzhuang Xi Caiping Zhu Guodong Liang Guoqing Hu Lafifa Jamal Jahangir Alam S. M. |
author_facet | Mingliang Ge Zhuangzhuang Xi Caiping Zhu Guodong Liang Guoqing Hu Lafifa Jamal Jahangir Alam S. M. |
author_sort | Mingliang Ge |
collection | DOAJ |
description | The magadiite–magnetite (MAG–Fe<sub>3</sub>O<sub>4</sub>) nanocomposite has great potential applications in the field of biomaterials research. It has been used as a novel magnetic sorbent, prepared by co-precipitation method. It has the dual advantage of having the magnetism of Fe<sub>3</sub>O<sub>4</sub> and the high adsorption capacity of pure magadiite (MAG). MAG–Fe<sub>3</sub>O<sub>4</sub> was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). The results showed that Fe<sub>3</sub>O<sub>4</sub> nanoparticles were deposited on the interlayer and surface of magadiite. MAG–Fe<sub>3</sub>O<sub>4</sub> was treated as an adsorbent for methylene blue (MB) removal from aqueous solutions. The adsorption properties of MAG–Fe<sub>3</sub>O<sub>4</sub> were investigated on methylene blue; however, the results showed that the adsorption performance of MAG–Fe<sub>3</sub>O<sub>4</sub> improved remarkably compared with MA and Fe<sub>3</sub>O<sub>4</sub>. The adsorption capacity of MAG–Fe<sub>3</sub>O<sub>4</sub> and the removal ratio of methylene blue were 93.7 mg/g and 96.2%, respectively (at 25 °C for 60 min, pH = 7, methylene blue solution of 100 mg/L, and the adsorbent dosage 1 g/L). In this research, the adsorption experimental data were fitted and well described using a pseudo-second-order kinetic model and a Langmuir adsorption isotherm model. The research results further showed that the adsorption performance of MAG–Fe<sub>3</sub>O<sub>4</sub> was better than that of MAG and Fe<sub>3</sub>O<sub>4</sub>. Moreover, the adsorption behavior of MB on MAG–Fe<sub>3</sub>O<sub>4</sub> was investigated to fit well in the pseudo-second-order kinetic model with the adsorption kinetics. The authors also concluded that the isothermal adsorption was followed by the Langmuir adsorption isotherm model; however, it was found that the adsorption of the MAG–Fe<sub>3</sub>O<sub>4</sub> nanocomposite was a monolayer adsorption. |
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spelling | doaj.art-b3eb435abced4db4b184f61c41aca3392022-12-22T03:08:40ZengMDPI AGPolymers2073-43602019-04-0111460710.3390/polym11040607polym11040607Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous SolutionsMingliang Ge0Zhuangzhuang Xi1Caiping Zhu2Guodong Liang3Guoqing Hu4Lafifa Jamal5Jahangir Alam S. M.6Key Laboratory of Polymer Processing Engineering of Ministry of Education, National Engineering Research Center of Novel Equipment for Polymer Processing, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaKey Laboratory of Polymer Processing Engineering of Ministry of Education, National Engineering Research Center of Novel Equipment for Polymer Processing, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaKey Laboratory of Polymer Processing Engineering of Ministry of Education, National Engineering Research Center of Novel Equipment for Polymer Processing, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaKey Laboratory of Polymeric Composite & Functional Materials of Ministry of Education, Sun Yat-Sen University, Guangzhou 510275, ChinaKey Laboratory of Polymer Processing Engineering of Ministry of Education, National Engineering Research Center of Novel Equipment for Polymer Processing, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaDepartment of Robotics & Mechatronics Engineering, University of Dhaka, Dhaka 1000, BangladeshKey Laboratory of Polymer Processing Engineering of Ministry of Education, National Engineering Research Center of Novel Equipment for Polymer Processing, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaThe magadiite–magnetite (MAG–Fe<sub>3</sub>O<sub>4</sub>) nanocomposite has great potential applications in the field of biomaterials research. It has been used as a novel magnetic sorbent, prepared by co-precipitation method. It has the dual advantage of having the magnetism of Fe<sub>3</sub>O<sub>4</sub> and the high adsorption capacity of pure magadiite (MAG). MAG–Fe<sub>3</sub>O<sub>4</sub> was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). The results showed that Fe<sub>3</sub>O<sub>4</sub> nanoparticles were deposited on the interlayer and surface of magadiite. MAG–Fe<sub>3</sub>O<sub>4</sub> was treated as an adsorbent for methylene blue (MB) removal from aqueous solutions. The adsorption properties of MAG–Fe<sub>3</sub>O<sub>4</sub> were investigated on methylene blue; however, the results showed that the adsorption performance of MAG–Fe<sub>3</sub>O<sub>4</sub> improved remarkably compared with MA and Fe<sub>3</sub>O<sub>4</sub>. The adsorption capacity of MAG–Fe<sub>3</sub>O<sub>4</sub> and the removal ratio of methylene blue were 93.7 mg/g and 96.2%, respectively (at 25 °C for 60 min, pH = 7, methylene blue solution of 100 mg/L, and the adsorbent dosage 1 g/L). In this research, the adsorption experimental data were fitted and well described using a pseudo-second-order kinetic model and a Langmuir adsorption isotherm model. The research results further showed that the adsorption performance of MAG–Fe<sub>3</sub>O<sub>4</sub> was better than that of MAG and Fe<sub>3</sub>O<sub>4</sub>. Moreover, the adsorption behavior of MB on MAG–Fe<sub>3</sub>O<sub>4</sub> was investigated to fit well in the pseudo-second-order kinetic model with the adsorption kinetics. The authors also concluded that the isothermal adsorption was followed by the Langmuir adsorption isotherm model; however, it was found that the adsorption of the MAG–Fe<sub>3</sub>O<sub>4</sub> nanocomposite was a monolayer adsorption.https://www.mdpi.com/2073-4360/11/4/607magneticnanocompositeFe<sub>3</sub>O<sub>4</sub>magadiiteadsorptionmethylene blue |
spellingShingle | Mingliang Ge Zhuangzhuang Xi Caiping Zhu Guodong Liang Guoqing Hu Lafifa Jamal Jahangir Alam S. M. Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions Polymers magnetic nanocomposite Fe<sub>3</sub>O<sub>4</sub> magadiite adsorption methylene blue |
title | Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions |
title_full | Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions |
title_fullStr | Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions |
title_full_unstemmed | Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions |
title_short | Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions |
title_sort | preparation and characterization of magadiite magnetite nanocomposite with its sorption performance analyses on removal of methylene blue from aqueous solutions |
topic | magnetic nanocomposite Fe<sub>3</sub>O<sub>4</sub> magadiite adsorption methylene blue |
url | https://www.mdpi.com/2073-4360/11/4/607 |
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