Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc
The common feature of the title compounds, [Zn(C5H10NO2S2)2(C10H8N2)]·2H2O, (I), and [Zn(C6H12NOS2)2(C10H8N2)], (II), is the location of the ZnII atoms on a twofold rotation axis. Further, each ZnII atom is chelated by two symmetry-equivalent and symmetrically coordinating dithiocarbamate ligands an...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016000700 |
| _version_ | 1818085059266084864 |
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| author | Siti Artikah M. Safbri Siti Nadiah Abdul Halim Edward R. T. Tiekink |
| author_facet | Siti Artikah M. Safbri Siti Nadiah Abdul Halim Edward R. T. Tiekink |
| author_sort | Siti Artikah M. Safbri |
| collection | DOAJ |
| description | The common feature of the title compounds, [Zn(C5H10NO2S2)2(C10H8N2)]·2H2O, (I), and [Zn(C6H12NOS2)2(C10H8N2)], (II), is the location of the ZnII atoms on a twofold rotation axis. Further, each ZnII atom is chelated by two symmetry-equivalent and symmetrically coordinating dithiocarbamate ligands and a 2,2′-bipyridine ligand. The resulting N2S4 coordination geometry is based on a highly distorted octahedron in each case. In the molecular packing of (I), supramolecular ladders mediated by O—H...O hydrogen bonding are found whereby the uprights are defined by {...HO(water)...HO(hydroxy)...}n chains parallel to the a axis and with the rungs defined by `Zn[S2CN(CH2CH2)2]2'. The water molecules connect the ladders into a supramolecular layer parallel to the ab plane via water-O—H...S and pyridyl-C—H...O(water) interactions, with the connections between layers being of the type pyridyl-C—H...S. In (II), supramolecular layers parallel to the ab plane are sustained by hydroxy-O—H...S hydrogen bonds with connections between layers being of the type pyridyl-C—H...S. |
| first_indexed | 2024-12-10T20:03:46Z |
| format | Article |
| id | doaj.art-b3ef66d68d1c4da4b0df3dc6514cc4eb |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-10T20:03:46Z |
| publishDate | 2016-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-b3ef66d68d1c4da4b0df3dc6514cc4eb2022-12-22T01:35:26ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-02-0172220320810.1107/S2056989016000700wm5262Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zincSiti Artikah M. Safbri0Siti Nadiah Abdul Halim1Edward R. T. Tiekink2Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, MalaysiaDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, MalaysiaCentre for Crystalline Materials, Faculty of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, MalaysiaThe common feature of the title compounds, [Zn(C5H10NO2S2)2(C10H8N2)]·2H2O, (I), and [Zn(C6H12NOS2)2(C10H8N2)], (II), is the location of the ZnII atoms on a twofold rotation axis. Further, each ZnII atom is chelated by two symmetry-equivalent and symmetrically coordinating dithiocarbamate ligands and a 2,2′-bipyridine ligand. The resulting N2S4 coordination geometry is based on a highly distorted octahedron in each case. In the molecular packing of (I), supramolecular ladders mediated by O—H...O hydrogen bonding are found whereby the uprights are defined by {...HO(water)...HO(hydroxy)...}n chains parallel to the a axis and with the rungs defined by `Zn[S2CN(CH2CH2)2]2'. The water molecules connect the ladders into a supramolecular layer parallel to the ab plane via water-O—H...S and pyridyl-C—H...O(water) interactions, with the connections between layers being of the type pyridyl-C—H...S. In (II), supramolecular layers parallel to the ab plane are sustained by hydroxy-O—H...S hydrogen bonds with connections between layers being of the type pyridyl-C—H...S.http://scripts.iucr.org/cgi-bin/paper?S2056989016000700crystal structurezincdithiocarbamatehydrogen bonding |
| spellingShingle | Siti Artikah M. Safbri Siti Nadiah Abdul Halim Edward R. T. Tiekink Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc Acta Crystallographica Section E: Crystallographic Communications crystal structure zinc dithiocarbamate hydrogen bonding |
| title | Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc |
| title_full | Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc |
| title_fullStr | Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc |
| title_full_unstemmed | Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc |
| title_short | Crystal structures of (2,2′-bipyridyl-κ2N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc |
| title_sort | crystal structures of 2 2 bipyridyl κ2n n bis n n bis 2 hydroxyethyl dithiocarbamato κ2s s zinc dihydrate and 2 2 bipyridyl κ2n n bis n 2 hydroxyethyl n isopropyldithiocarbamato κ2s s zinc |
| topic | crystal structure zinc dithiocarbamate hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016000700 |
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