The Influence of Yb Doping and Sintering Conditions on the Magnetocaloric and Mechanical Properties of EuS

For this work, europium monosulfide (EuS) powders were prepared by sulfurizing Eu<sub>2</sub>O<sub>3</sub> powder with CS<sub>2</sub> gas. The synthesized EuS powders were sintered by SPS at temperatures in the 800–1600 °C range for 0.33–1 h at 50 MPa under vacuum...

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Bibliographic Details
Main Authors: Liang Li, Yuqi Chen, Junbao He, Aiguo Zhou
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/17/5660
Description
Summary:For this work, europium monosulfide (EuS) powders were prepared by sulfurizing Eu<sub>2</sub>O<sub>3</sub> powder with CS<sub>2</sub> gas. The synthesized EuS powders were sintered by SPS at temperatures in the 800–1600 °C range for 0.33–1 h at 50 MPa under vacuum conditions. The influences of Yb doping and sintering conditions on the magnetocaloric and mechanical properties of EuS were investigated systematically. An increase in sintering temperature caused the rise of lattice parameters of EuS, whereas Yb doping caused them to drop. SEM showed that the grain size of the EuS increased with sintering temperatures in the 1000–1400 °C range. Higher sintering temperatures can enlarge the magnetizability and saturation magnetization of EuS compact. On the contrary, Yb doping can weaken the magnetizability and saturation magnetization of EuS compact. All sintered polycrystalline EuS compacts had weaker thermomagnetic irreversibility and lower magnetic anisotropy.
ISSN:1420-3049