Synthesis and Characterization of some New Mesoionic 1,3-Thiazolium-5-thiolates via Cyclodehydration and in situ 1,3-Dipolar Cycloaddition/Cycloreversion

Synthesis and Characterization of some New Mesoionic 1,3-Thiazolium-5-thiolates via Cyclodehydration and in situ 1,3-Dipolar Cycloaddition/Cycloreversion

The title compounds were synthesized from C-aryl-N-methylglycines by Naroylation followed by a cyclodehydration to form the corresponding 1,3-oxazolium-5-olates. These were not isolated but converted to the title compounds by an in situ 1,3-dipolar cycloaddition/cycloreversion sequence using carbon...

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Bibliographic Details
Main Authors: Maria Joaquina Vieira, Aderson de Farias Dias, Alfredo Mayall Simas, Joseph Miller, Petrônio Filgueiras de Athayde Filho, Bruno Freitas Lira
Format: Article
Language:English
Published: MDPI AG 2002-11-01
Series:Molecules
Subjects:
Mesoionic 1
3-thiazolium-5-thiolates
Synthesis
Characterization
Online Access:http://www.mdpi.com/1420-3049/7/11/791/

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