Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides
A novel method of photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides has been developed. Although the arylation reactions with triarylbismuthines are usually catalyzed by transition-metal complexes, the present arylation of diaryl diselenides with...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Beilstein-Institut
2013-06-01
|
| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.9.127 |
| _version_ | 1818675506603622400 |
|---|---|
| author | Yohsuke Kobiki Shin-ichi Kawaguchi Takashi Ohe Akiya Ogawa |
| author_facet | Yohsuke Kobiki Shin-ichi Kawaguchi Takashi Ohe Akiya Ogawa |
| author_sort | Yohsuke Kobiki |
| collection | DOAJ |
| description | A novel method of photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides has been developed. Although the arylation reactions with triarylbismuthines are usually catalyzed by transition-metal complexes, the present arylation of diaryl diselenides with triarylbismuthines proceeds upon photoirradiation in the absence of transition-metal catalysts. A variety of unsymmetrical diaryl selenides can be conveniently prepared by using this arylation method. |
| first_indexed | 2024-12-17T08:28:40Z |
| format | Article |
| id | doaj.art-b44667b7cd9c486e9d5f9933cc0f68e9 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-17T08:28:40Z |
| publishDate | 2013-06-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-b44667b7cd9c486e9d5f9933cc0f68e92022-12-21T21:56:41ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972013-06-01911141114710.3762/bjoc.9.1271860-5397-9-127Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenidesYohsuke Kobiki0Shin-ichi Kawaguchi1Takashi Ohe2Akiya Ogawa3Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanA novel method of photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides has been developed. Although the arylation reactions with triarylbismuthines are usually catalyzed by transition-metal complexes, the present arylation of diaryl diselenides with triarylbismuthines proceeds upon photoirradiation in the absence of transition-metal catalysts. A variety of unsymmetrical diaryl selenides can be conveniently prepared by using this arylation method.https://doi.org/10.3762/bjoc.9.127arylationunsymmetrical diaryl selenidefree radicalorganobismuthphotoinduced reaction |
| spellingShingle | Yohsuke Kobiki Shin-ichi Kawaguchi Takashi Ohe Akiya Ogawa Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides Beilstein Journal of Organic Chemistry arylation unsymmetrical diaryl selenide free radical organobismuth photoinduced reaction |
| title | Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides |
| title_full | Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides |
| title_fullStr | Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides |
| title_full_unstemmed | Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides |
| title_short | Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides |
| title_sort | photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides |
| topic | arylation unsymmetrical diaryl selenide free radical organobismuth photoinduced reaction |
| url | https://doi.org/10.3762/bjoc.9.127 |
| work_keys_str_mv | AT yohsukekobiki photoinducedsynthesisofunsymmetricaldiarylselenidesfromtriarylbismuthinesanddiaryldiselenides AT shinichikawaguchi photoinducedsynthesisofunsymmetricaldiarylselenidesfromtriarylbismuthinesanddiaryldiselenides AT takashiohe photoinducedsynthesisofunsymmetricaldiarylselenidesfromtriarylbismuthinesanddiaryldiselenides AT akiyaogawa photoinducedsynthesisofunsymmetricaldiarylselenidesfromtriarylbismuthinesanddiaryldiselenides |