Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of Methane
In this study, Ce0.85-xLa0.15CaxO2-δ was synthesized using sol-gel combustion method and appliedfor partial oxidation of methane (POM). The physicochemical properties of catalyst were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (ED...
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2021-09-01
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Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
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Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/10528 |
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author | Qassam Sarmad U. M. Khan Mustafa Anwar A. H. Khoja M. Ali Z. S. Khan Andanastuti Muchtar M. R. Somalu |
author_facet | Qassam Sarmad U. M. Khan Mustafa Anwar A. H. Khoja M. Ali Z. S. Khan Andanastuti Muchtar M. R. Somalu |
author_sort | Qassam Sarmad |
collection | DOAJ |
description | In this study, Ce0.85-xLa0.15CaxO2-δ was synthesized using sol-gel combustion method and appliedfor partial oxidation of methane (POM). The physicochemical properties of catalyst were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and thermogravimetric analysis (TGA). Material shows a pure cubical structure and is highly stable up to 850 °C. The performance testing indicated the conversion of CH4 is 65% and selectivity of H2 and CO are 28% and 8%, respectively. The performance indicated the catalyst has a potential to be used for partial oxidation of methane on a larger scale. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
first_indexed | 2024-03-11T22:51:00Z |
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institution | Directory Open Access Journal |
issn | 1978-2993 |
language | English |
last_indexed | 2024-03-11T22:51:00Z |
publishDate | 2021-09-01 |
publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
record_format | Article |
series | Bulletin of Chemical Reaction Engineering & Catalysis |
spelling | doaj.art-b45ae19fdcb643a1988b23458fa5fd7a2023-09-22T03:36:06ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932021-09-0116354855410.9767/bcrec.16.3.10528.548-5544881Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of MethaneQassam Sarmad0https://orcid.org/0000-0003-0005-3447U. M. Khan1Mustafa Anwar2A. H. Khoja3M. Ali4Z. S. Khan5Andanastuti Muchtar6https://orcid.org/0000-0002-1599-8964M. R. Somalu7https://orcid.org/0000-0003-1667-693XDepartment of Energy Systems Engineering, U.S.-Pakistan Centre for Advanced Studies in Energy (USPCAS-E), National University of Sciences & Technology (NUST), H-12 Sector (44000) Islamabad, PakistanDepartment of Energy Systems Engineering, U.S.-Pakistan Centre for Advanced Studies in Energy (USPCAS-E), National University of Sciences & Technology (NUST), H-12 Sector (44000) Islamabad, PakistanDepartment of Energy Systems Engineering, United States-Pakistan Centre for Advanced Studies in Energy (USPCAS-E), National University of Sciences & Technology (NUST), Islamabad, PakistanFossil Fuel Laboratory, Department of Thermal Energy Engineering, U.S.-Pakistan Centre for Advanced Studies in Energy (USPCAS-E), National University of Sciences & Technology (NUST), H-12 Sector (44000) Islamabad, PakistanFuel Cell Institute, Universiti Kebangsaan Malaysia, 43600, UKM Bangi, Selangor, MalaysiaDepartment of Energy Systems Engineering, U.S.-Pakistan Centre for Advanced Studies in Energy (USPCAS-E), National University of Sciences & Technology (NUST), H-12 Sector (44000) Islamabad, PakistanFuel Cell Institute, Universiti Kebangsaan Malaysia, 43600, UKM Bangi, Selangor, MalaysiaFuel Cell Institute, Universiti Kebangsaan Malaysia, 43600, UKM Bangi, Selangor, MalaysiaIn this study, Ce0.85-xLa0.15CaxO2-δ was synthesized using sol-gel combustion method and appliedfor partial oxidation of methane (POM). The physicochemical properties of catalyst were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and thermogravimetric analysis (TGA). Material shows a pure cubical structure and is highly stable up to 850 °C. The performance testing indicated the conversion of CH4 is 65% and selectivity of H2 and CO are 28% and 8%, respectively. The performance indicated the catalyst has a potential to be used for partial oxidation of methane on a larger scale. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/10528partial oxidation of methanepomhydrogen productionce0.85-xla0.15caxo2-δ |
spellingShingle | Qassam Sarmad U. M. Khan Mustafa Anwar A. H. Khoja M. Ali Z. S. Khan Andanastuti Muchtar M. R. Somalu Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of Methane Bulletin of Chemical Reaction Engineering & Catalysis partial oxidation of methane pom hydrogen production ce0.85-xla0.15caxo2-δ |
title | Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of Methane |
title_full | Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of Methane |
title_fullStr | Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of Methane |
title_full_unstemmed | Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of Methane |
title_short | Catalytic Performance of Calcium-Lanthanum co-doped Ceria (Ce0.85-xLa0.15CaxO2-δ) in Partial Oxidation of Methane |
title_sort | catalytic performance of calcium lanthanum co doped ceria ce0 85 xla0 15caxo2 δ in partial oxidation of methane |
topic | partial oxidation of methane pom hydrogen production ce0.85-xla0.15caxo2-δ |
url | https://journal.bcrec.id/index.php/bcrec/article/view/10528 |
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