Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment

In this paper, the use of Metal-Organic Framework (MOF) materials as an option for the energy efficiency enhancement of HVAC systems is investigated. In particular, the possibility of using MOFs as dehumidifying materials to reduce the latent load associated with the moisture content of the airflows...

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Main Authors: Andrea Rocchetti, Martina Lippi, Luca Socci, Paride Gullo, Vahid Khorshidi, Lorenzo Talluri
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/15/23/8908
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author Andrea Rocchetti
Martina Lippi
Luca Socci
Paride Gullo
Vahid Khorshidi
Lorenzo Talluri
author_facet Andrea Rocchetti
Martina Lippi
Luca Socci
Paride Gullo
Vahid Khorshidi
Lorenzo Talluri
author_sort Andrea Rocchetti
collection DOAJ
description In this paper, the use of Metal-Organic Framework (MOF) materials as an option for the energy efficiency enhancement of HVAC systems is investigated. In particular, the possibility of using MOFs as dehumidifying materials to reduce the latent load associated with the moisture content of the airflows is studied. A literature review is proposed, highlighting the benefits of using MOFs instead of other adsorbents (e.g., silica-gel) and discussing the unique features (high water uptake capacity and low regeneration temperatures) that make MOFs a preferential desiccant. The possibility to finely tune these properties is also underlined, reporting some explicative examples. A theoretical proposal of a psychrometric transformation, to be performed in a HVAC system equipped with a MOF-Assisted Dehumidifier (MAD), is presented. This transformation is compared with a traditional one (cooling and dehumidification operated by a cooling coil with low temperatures of the coolant). The preliminary numerical simulations, conducted on a reference case study in Florence, Italy, show an estimated energy saving of 30–50%, leading us to consider the use of this technology as a very competitive one in the air-conditioning sector.
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spelling doaj.art-b46390327a7e4a53a802d75afbd8135d2023-11-24T10:52:18ZengMDPI AGEnergies1996-10732022-11-011523890810.3390/en15238908Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical AssessmentAndrea Rocchetti0Martina Lippi1Luca Socci2Paride Gullo3Vahid Khorshidi4Lorenzo Talluri5Department of Industrial Engineering, University of Florence, 50139 Florence, ItalyDepartment of Industrial Engineering, University of Florence, 50139 Florence, ItalyDepartment of Industrial Engineering, University of Florence, 50139 Florence, ItalyDepartment of Mechanical and Electrical Engineering, University of Southern Denmark, 6400 Sønderborg, DenmarkRAC R&D Innovation Lab, Danfoss A/S, 6430 Nordborg, DenmarkDepartment of Industrial Engineering, University of Florence, 50139 Florence, ItalyIn this paper, the use of Metal-Organic Framework (MOF) materials as an option for the energy efficiency enhancement of HVAC systems is investigated. In particular, the possibility of using MOFs as dehumidifying materials to reduce the latent load associated with the moisture content of the airflows is studied. A literature review is proposed, highlighting the benefits of using MOFs instead of other adsorbents (e.g., silica-gel) and discussing the unique features (high water uptake capacity and low regeneration temperatures) that make MOFs a preferential desiccant. The possibility to finely tune these properties is also underlined, reporting some explicative examples. A theoretical proposal of a psychrometric transformation, to be performed in a HVAC system equipped with a MOF-Assisted Dehumidifier (MAD), is presented. This transformation is compared with a traditional one (cooling and dehumidification operated by a cooling coil with low temperatures of the coolant). The preliminary numerical simulations, conducted on a reference case study in Florence, Italy, show an estimated energy saving of 30–50%, leading us to consider the use of this technology as a very competitive one in the air-conditioning sector.https://www.mdpi.com/1996-1073/15/23/8908metal-organic frameworkwater-uptakeHVACdehumidificationenergy-saving
spellingShingle Andrea Rocchetti
Martina Lippi
Luca Socci
Paride Gullo
Vahid Khorshidi
Lorenzo Talluri
Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment
Energies
metal-organic framework
water-uptake
HVAC
dehumidification
energy-saving
title Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment
title_full Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment
title_fullStr Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment
title_full_unstemmed Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment
title_short Metal-Organic Framework Adsorbent Materials in HVAC Systems: General Survey and Theoretical Assessment
title_sort metal organic framework adsorbent materials in hvac systems general survey and theoretical assessment
topic metal-organic framework
water-uptake
HVAC
dehumidification
energy-saving
url https://www.mdpi.com/1996-1073/15/23/8908
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AT paridegullo metalorganicframeworkadsorbentmaterialsinhvacsystemsgeneralsurveyandtheoreticalassessment
AT vahidkhorshidi metalorganicframeworkadsorbentmaterialsinhvacsystemsgeneralsurveyandtheoreticalassessment
AT lorenzotalluri metalorganicframeworkadsorbentmaterialsinhvacsystemsgeneralsurveyandtheoreticalassessment