A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by Clusteroluminescence
Abstract Clusteroluminescence (CL) has recently gained significant attention due to its unique through‐space interactions associated with a high dependence on the aggregation of subgroups. These distinct features could easily transform the stimuli into visual fluorescence and monitor the fluctuation...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2024-01-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202304946 |
| _version_ | 1797365311445401600 |
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| author | Xiang Chen Chenxi Hu Yang Wang Ting Li Jie Jiang Jing Huang Shibo Wang Weifu Dong Jinliang Qiao |
| author_facet | Xiang Chen Chenxi Hu Yang Wang Ting Li Jie Jiang Jing Huang Shibo Wang Weifu Dong Jinliang Qiao |
| author_sort | Xiang Chen |
| collection | DOAJ |
| description | Abstract Clusteroluminescence (CL) has recently gained significant attention due to its unique through‐space interactions associated with a high dependence on the aggregation of subgroups. These distinct features could easily transform the stimuli into visual fluorescence and monitor the fluctuation of the environment but have not received sufficient attention before. In this work, supramolecular films are designed based on the neutralization reaction of anhydride groups and the self‐assembly of dynamic covalent disulfide bonds in NaOH aqueous solution. The self‐assembly of hydrophilic carboxylate chromophores and hydrophobic disulfide‐containing five‐membered rings could be observed by the variation of the aggregation state of carboxylate in CL. Furthermore, the dynamic cross‐linking films obtained with water‐sensitive carboxylate chromophores could alter the aggregation distance stimulated by surrounding water vapor, causing the emission wavelength to change from 534 to 508 nm by varying the relative humidity. This work not only provides an approach to monitor the self‐assembly of clusteroluminogens but also offers new strategies for designing stimuli‐responsive materials that utilize the intrinsic features of CL. |
| first_indexed | 2024-03-08T16:48:18Z |
| format | Article |
| id | doaj.art-b48f1987049443d885e0d228922b8867 |
| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2024-03-08T16:48:18Z |
| publishDate | 2024-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj.art-b48f1987049443d885e0d228922b88672024-01-05T08:26:58ZengWileyAdvanced Science2198-38442024-01-01111n/an/a10.1002/advs.202304946A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by ClusteroluminescenceXiang Chen0Chenxi Hu1Yang Wang2Ting Li3Jie Jiang4Jing Huang5Shibo Wang6Weifu Dong7Jinliang Qiao8The Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University 1800 Lihu Road Wuxi 214122 ChinaSINOPEC Beijing Research Institute of Chemical Industry Beijing 100013 ChinaThe Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University 1800 Lihu Road Wuxi 214122 ChinaThe Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University 1800 Lihu Road Wuxi 214122 ChinaThe Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University 1800 Lihu Road Wuxi 214122 ChinaThe Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University 1800 Lihu Road Wuxi 214122 ChinaThe Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University 1800 Lihu Road Wuxi 214122 ChinaThe Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University 1800 Lihu Road Wuxi 214122 ChinaSINOPEC Beijing Research Institute of Chemical Industry Beijing 100013 ChinaAbstract Clusteroluminescence (CL) has recently gained significant attention due to its unique through‐space interactions associated with a high dependence on the aggregation of subgroups. These distinct features could easily transform the stimuli into visual fluorescence and monitor the fluctuation of the environment but have not received sufficient attention before. In this work, supramolecular films are designed based on the neutralization reaction of anhydride groups and the self‐assembly of dynamic covalent disulfide bonds in NaOH aqueous solution. The self‐assembly of hydrophilic carboxylate chromophores and hydrophobic disulfide‐containing five‐membered rings could be observed by the variation of the aggregation state of carboxylate in CL. Furthermore, the dynamic cross‐linking films obtained with water‐sensitive carboxylate chromophores could alter the aggregation distance stimulated by surrounding water vapor, causing the emission wavelength to change from 534 to 508 nm by varying the relative humidity. This work not only provides an approach to monitor the self‐assembly of clusteroluminogens but also offers new strategies for designing stimuli‐responsive materials that utilize the intrinsic features of CL.https://doi.org/10.1002/advs.202304946clusteroluminescencedynamic bondself‐assemblestimuli‐responsive materials |
| spellingShingle | Xiang Chen Chenxi Hu Yang Wang Ting Li Jie Jiang Jing Huang Shibo Wang Weifu Dong Jinliang Qiao A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by Clusteroluminescence Advanced Science clusteroluminescence dynamic bond self‐assemble stimuli‐responsive materials |
| title | A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by Clusteroluminescence |
| title_full | A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by Clusteroluminescence |
| title_fullStr | A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by Clusteroluminescence |
| title_full_unstemmed | A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by Clusteroluminescence |
| title_short | A Self‐Assemble Supramolecular Film with Humidity Visualization Enabled by Clusteroluminescence |
| title_sort | self assemble supramolecular film with humidity visualization enabled by clusteroluminescence |
| topic | clusteroluminescence dynamic bond self‐assemble stimuli‐responsive materials |
| url | https://doi.org/10.1002/advs.202304946 |
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