catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate]
The asymmetric unit of the title compound, {[Zn(C7H7O2)2(C10H8N2)]·4H2O}n, contains a highly distorted octahedral ZnII metal center strongly coordinated by two N atoms of two 4,4′-bipyridine (4,4′-bipy) ligands and chelated by two 4-methylbenzoate anions. The...
| Format: | Article |
|---|---|
| Language: | English |
| Published: |
International Union of Crystallography
2009-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809005571 |
| _version_ | 1819281129068298240 |
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| collection | DOAJ |
| description | The asymmetric unit of the title compound, {[Zn(C7H7O2)2(C10H8N2)]·4H2O}n, contains a highly distorted octahedral ZnII metal center strongly coordinated by two N atoms of two 4,4′-bipyridine (4,4′-bipy) ligands and chelated by two 4-methylbenzoate anions. The crystallographic inversion center and glide plane present at the center of the C—C single bond of 4,4′-bipy, along with the cis coordination motif of the 4,4′-bipy, lead to one-dimensional zigzag chains. There are a large number of water molecules in the crystal structure, which also form one-dimensional chains through O—H...O hydrogen bonds. |
| first_indexed | 2024-12-24T00:54:47Z |
| format | Article |
| id | doaj.art-b4ac7258d7b84ace954e178bc6d7f81d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:54:47Z |
| publishDate | 2009-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b4ac7258d7b84ace954e178bc6d7f81d2022-12-21T17:23:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m354m35410.1107/S1600536809005571catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate]The asymmetric unit of the title compound, {[Zn(C7H7O2)2(C10H8N2)]·4H2O}n, contains a highly distorted octahedral ZnII metal center strongly coordinated by two N atoms of two 4,4′-bipyridine (4,4′-bipy) ligands and chelated by two 4-methylbenzoate anions. The crystallographic inversion center and glide plane present at the center of the C—C single bond of 4,4′-bipy, along with the cis coordination motif of the 4,4′-bipy, lead to one-dimensional zigzag chains. There are a large number of water molecules in the crystal structure, which also form one-dimensional chains through O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809005571 |
| spellingShingle | catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate] Acta Crystallographica Section E |
| title | catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate] |
| title_full | catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate] |
| title_fullStr | catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate] |
| title_full_unstemmed | catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate] |
| title_short | catena-Poly[[[bis(4-methylbenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] tetrahydrate] |
| title_sort | catena poly bis 4 methylbenzoato amp 954 2o o amp 8242 zinc ii amp 956 4 4 amp 8242 bipyridine amp 954 2n n amp 8242 tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809005571 |