Novel Schiff Bases of C-Methylresorcinarene Derivatives
The article presents the synthesis and properties of two new Schiff bases of resorcinarene derivatives. The Schiff bases were obtained by the reaction of formylresorcinarene with aromatic (<i>o</i>-aminophenol) and aliphatic (<i>N</i>,<i>N</i>-dimethyldiaminoethan...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-11-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2022/4/M1505 |
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| author | Albina Y. Ziganshina Olga S. Saranova Rezeda R. Fazleeva Vitaly V. Yanilkin Igor S. Antipin |
| author_facet | Albina Y. Ziganshina Olga S. Saranova Rezeda R. Fazleeva Vitaly V. Yanilkin Igor S. Antipin |
| author_sort | Albina Y. Ziganshina |
| collection | DOAJ |
| description | The article presents the synthesis and properties of two new Schiff bases of resorcinarene derivatives. The Schiff bases were obtained by the reaction of formylresorcinarene with aromatic (<i>o</i>-aminophenol) and aliphatic (<i>N</i>,<i>N</i>-dimethyldiaminoethane) amines in chloroform. The synthesized Schiff bases exist in equilibrium of several tautomers, as evident from the IR, UV, NMR spectra and cyclic voltammetry data analysis. In DMF, methanol, and acetonitrile, the tautomeric equilibrium is shifted toward the enol-imine tautomers. |
| first_indexed | 2024-03-09T16:03:32Z |
| format | Article |
| id | doaj.art-b4b1d3cb32ab4160a4e68ec8f8c5dafb |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-09T16:03:32Z |
| publishDate | 2022-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-b4b1d3cb32ab4160a4e68ec8f8c5dafb2023-11-24T16:54:26ZengMDPI AGMolbank1422-85992022-11-0120224M150510.3390/M1505Novel Schiff Bases of C-Methylresorcinarene DerivativesAlbina Y. Ziganshina0Olga S. Saranova1Rezeda R. Fazleeva2Vitaly V. Yanilkin3Igor S. Antipin4A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, RussiaDepartment of Organic Chemistry, Alexander Butlerov Institute of Chemistry, Kazan Federal University, Lobachevsky Str. 1/29, 420008 Kazan, RussiaA.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, RussiaA.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, RussiaDepartment of Organic Chemistry, Alexander Butlerov Institute of Chemistry, Kazan Federal University, Lobachevsky Str. 1/29, 420008 Kazan, RussiaThe article presents the synthesis and properties of two new Schiff bases of resorcinarene derivatives. The Schiff bases were obtained by the reaction of formylresorcinarene with aromatic (<i>o</i>-aminophenol) and aliphatic (<i>N</i>,<i>N</i>-dimethyldiaminoethane) amines in chloroform. The synthesized Schiff bases exist in equilibrium of several tautomers, as evident from the IR, UV, NMR spectra and cyclic voltammetry data analysis. In DMF, methanol, and acetonitrile, the tautomeric equilibrium is shifted toward the enol-imine tautomers.https://www.mdpi.com/1422-8599/2022/4/M1505schiff basesalicyliminesalenaminoethylimineresorcinareneimine |
| spellingShingle | Albina Y. Ziganshina Olga S. Saranova Rezeda R. Fazleeva Vitaly V. Yanilkin Igor S. Antipin Novel Schiff Bases of C-Methylresorcinarene Derivatives Molbank schiff base salicylimine salen aminoethylimine resorcinarene imine |
| title | Novel Schiff Bases of C-Methylresorcinarene Derivatives |
| title_full | Novel Schiff Bases of C-Methylresorcinarene Derivatives |
| title_fullStr | Novel Schiff Bases of C-Methylresorcinarene Derivatives |
| title_full_unstemmed | Novel Schiff Bases of C-Methylresorcinarene Derivatives |
| title_short | Novel Schiff Bases of C-Methylresorcinarene Derivatives |
| title_sort | novel schiff bases of c methylresorcinarene derivatives |
| topic | schiff base salicylimine salen aminoethylimine resorcinarene imine |
| url | https://www.mdpi.com/1422-8599/2022/4/M1505 |
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