Corncob waste as a potential filler in biocomposites: A decision towards sustainability

Waste resource utilization is of utmost importance today in order to promote circular economy and sustainable development. The current research work focuses on utilizing post-consumer corncob (CC) waste into value-added products by exploring its potential as a filler/additive in polypropylene (PP) c...

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Main Authors: Sandeep Gairola, Tejas Pramod Naik, Shishir Sinha, Inderdeep Singh
Format: Article
Language:English
Published: Elsevier 2022-10-01
Series:Composites Part C: Open Access
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666682022000809
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author Sandeep Gairola
Tejas Pramod Naik
Shishir Sinha
Inderdeep Singh
author_facet Sandeep Gairola
Tejas Pramod Naik
Shishir Sinha
Inderdeep Singh
author_sort Sandeep Gairola
collection DOAJ
description Waste resource utilization is of utmost importance today in order to promote circular economy and sustainable development. The current research work focuses on utilizing post-consumer corncob (CC) waste into value-added products by exploring its potential as a filler/additive in polypropylene (PP) composites. If successful, the added fillers will substitute 5-20% PP without compromising the functional requirements of non-structural (non-load bearing) products. Corncob filler (CCF) at four-filler loadings (5, 10, 15, and 20 wt.%) and two variants of particle size (S1-100-355 µm and S2-355-710 µm) was melt-compounded using an extruder and then injection molded into composite samples. The effect of filler size and loading was investigated on water diffusion kinetics, mechanical, thermal, and flammability characteristics for analyzing the performance of developed materials during in-service conditions. Thermal and flammability characteristics were analyzed by thermo-gravimetric analysis (TGA), Ul-94 horizontal burning (HB), and limiting oxygen index (LOI) test. CCF-S1 exhibited better mechanical properties with higher tensile and flexural modulus than CCF-S2. For 10 wt. % loading, lower size (S1 filler) showed 5.85% and 2.94% increase in tensile and flexural modulus, respectively than higher filler size S2. CCF-S1 filled composites record lowered HB rate than S2 filler with no notable change in LOI values. The results revealed the possible reuse and utilization of CCF as a reinforcing filler at 10% loading with a filler size of 100-355 µm. The properties achieved using CCF and extrusion injection molding process are significant enough for non-structural applications such as paper weight, tableware, mementos etc.
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spelling doaj.art-b4bd1fc4e20b4b68be15d2ff63a57ce12022-12-22T04:13:37ZengElsevierComposites Part C: Open Access2666-68202022-10-019100317Corncob waste as a potential filler in biocomposites: A decision towards sustainabilitySandeep Gairola0Tejas Pramod Naik1Shishir Sinha2Inderdeep Singh3Centre of Excellence in Disaster Mitigation and Management, Indian Institute of Technology, Roorkee, IndiaMechanical and Industrial Engineering Department, Indian Institute of Technology, Roorkee, IndiaCentre of Excellence in Disaster Mitigation and Management, Indian Institute of Technology, Roorkee, India; Chemical Engineering Department, Indian Institute of Technology, Roorkee, IndiaCentre of Excellence in Disaster Mitigation and Management, Indian Institute of Technology, Roorkee, India; Mechanical and Industrial Engineering Department, Indian Institute of Technology, Roorkee, India; Corresponding author at: Mechanical and Industrial Engineering Department, Indian Institute of Technology Roorkee, Roorkee, India.Waste resource utilization is of utmost importance today in order to promote circular economy and sustainable development. The current research work focuses on utilizing post-consumer corncob (CC) waste into value-added products by exploring its potential as a filler/additive in polypropylene (PP) composites. If successful, the added fillers will substitute 5-20% PP without compromising the functional requirements of non-structural (non-load bearing) products. Corncob filler (CCF) at four-filler loadings (5, 10, 15, and 20 wt.%) and two variants of particle size (S1-100-355 µm and S2-355-710 µm) was melt-compounded using an extruder and then injection molded into composite samples. The effect of filler size and loading was investigated on water diffusion kinetics, mechanical, thermal, and flammability characteristics for analyzing the performance of developed materials during in-service conditions. Thermal and flammability characteristics were analyzed by thermo-gravimetric analysis (TGA), Ul-94 horizontal burning (HB), and limiting oxygen index (LOI) test. CCF-S1 exhibited better mechanical properties with higher tensile and flexural modulus than CCF-S2. For 10 wt. % loading, lower size (S1 filler) showed 5.85% and 2.94% increase in tensile and flexural modulus, respectively than higher filler size S2. CCF-S1 filled composites record lowered HB rate than S2 filler with no notable change in LOI values. The results revealed the possible reuse and utilization of CCF as a reinforcing filler at 10% loading with a filler size of 100-355 µm. The properties achieved using CCF and extrusion injection molding process are significant enough for non-structural applications such as paper weight, tableware, mementos etc.http://www.sciencedirect.com/science/article/pii/S2666682022000809CorncobLignocellulosicThermoplastic compositesFick's diffusionThermal stabilityFlammability
spellingShingle Sandeep Gairola
Tejas Pramod Naik
Shishir Sinha
Inderdeep Singh
Corncob waste as a potential filler in biocomposites: A decision towards sustainability
Composites Part C: Open Access
Corncob
Lignocellulosic
Thermoplastic composites
Fick's diffusion
Thermal stability
Flammability
title Corncob waste as a potential filler in biocomposites: A decision towards sustainability
title_full Corncob waste as a potential filler in biocomposites: A decision towards sustainability
title_fullStr Corncob waste as a potential filler in biocomposites: A decision towards sustainability
title_full_unstemmed Corncob waste as a potential filler in biocomposites: A decision towards sustainability
title_short Corncob waste as a potential filler in biocomposites: A decision towards sustainability
title_sort corncob waste as a potential filler in biocomposites a decision towards sustainability
topic Corncob
Lignocellulosic
Thermoplastic composites
Fick's diffusion
Thermal stability
Flammability
url http://www.sciencedirect.com/science/article/pii/S2666682022000809
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AT tejaspramodnaik corncobwasteasapotentialfillerinbiocompositesadecisiontowardssustainability
AT shishirsinha corncobwasteasapotentialfillerinbiocompositesadecisiontowardssustainability
AT inderdeepsingh corncobwasteasapotentialfillerinbiocompositesadecisiontowardssustainability