Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols Production

In recent years, research on the epoxidation of fatty acids has attracted considerable attention due to the growing demand for eco-friendly epoxides generated from vegetable oils. Commercially available epoxides are primarily derived from petroleum and animal fats, which are non-environmentally frie...

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Main Authors: Ismail Md Rasib, Mohd Zulkpli Ab Kadir, Intan Suhada Azmi, Mohammad'Aathif Addli, Noorfazlida Mohamed, Mohamad Zarqani Yeop, Mohd Azril Riduan, Mohd Jumain Jalil
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2023-12-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/14233
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author Ismail Md Rasib
Mohd Zulkpli Ab Kadir
Intan Suhada Azmi
Mohammad'Aathif Addli
Noorfazlida Mohamed
Mohamad Zarqani Yeop
Mohd Azril Riduan
Mohd Jumain Jalil
author_facet Ismail Md Rasib
Mohd Zulkpli Ab Kadir
Intan Suhada Azmi
Mohammad'Aathif Addli
Noorfazlida Mohamed
Mohamad Zarqani Yeop
Mohd Azril Riduan
Mohd Jumain Jalil
author_sort Ismail Md Rasib
collection DOAJ
description In recent years, research on the epoxidation of fatty acids has attracted considerable attention due to the growing demand for eco-friendly epoxides generated from vegetable oils. Commercially available epoxides are primarily derived from petroleum and animal fats, which are non-environmentally friendly sources. Epoxide is a crucial chemical precursor for the manufacture of alcohols, glycols, and polymers such as polyesters and epoxy resin. The optimal process parameters were determined using the one factor at a time (OFAT) technique. This study's purpose is to identify the optimal process parameter for agitation speed in relation to the oxirane ring opening of epoxidized oleic acid. The result at 100 rpm and sulfuric acid as catalyst are the optimal process setting for achieving maximal relative oxirane conversion (93 %). Then, the ring opening formation's identity was validated using Fourier Transform Infrared (FTIR).
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spelling doaj.art-b4c200281e4847e9a7097fe6e4c42f462023-12-15T23:50:22ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162023-12-0110610.3303/CET23106173Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols ProductionIsmail Md RasibMohd Zulkpli Ab KadirIntan Suhada AzmiMohammad'Aathif AddliNoorfazlida MohamedMohamad Zarqani YeopMohd Azril RiduanMohd Jumain JalilIn recent years, research on the epoxidation of fatty acids has attracted considerable attention due to the growing demand for eco-friendly epoxides generated from vegetable oils. Commercially available epoxides are primarily derived from petroleum and animal fats, which are non-environmentally friendly sources. Epoxide is a crucial chemical precursor for the manufacture of alcohols, glycols, and polymers such as polyesters and epoxy resin. The optimal process parameters were determined using the one factor at a time (OFAT) technique. This study's purpose is to identify the optimal process parameter for agitation speed in relation to the oxirane ring opening of epoxidized oleic acid. The result at 100 rpm and sulfuric acid as catalyst are the optimal process setting for achieving maximal relative oxirane conversion (93 %). Then, the ring opening formation's identity was validated using Fourier Transform Infrared (FTIR).https://www.cetjournal.it/index.php/cet/article/view/14233
spellingShingle Ismail Md Rasib
Mohd Zulkpli Ab Kadir
Intan Suhada Azmi
Mohammad'Aathif Addli
Noorfazlida Mohamed
Mohamad Zarqani Yeop
Mohd Azril Riduan
Mohd Jumain Jalil
Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols Production
Chemical Engineering Transactions
title Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols Production
title_full Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols Production
title_fullStr Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols Production
title_full_unstemmed Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols Production
title_short Chemical Modification of Oleic Acid Derived Palm Oil as Chemical Processor for Polyols Production
title_sort chemical modification of oleic acid derived palm oil as chemical processor for polyols production
url https://www.cetjournal.it/index.php/cet/article/view/14233
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