Development and study of iron-based nanoadsorbents

The application of an innovative, simple and low cost method was tested for the preparation of nanocrystalline iron hydroxides and oxyhydroxides; different iron precursors have been earlier used and combined to different volatile precipitating agents. The examined in the present product, akaganéite...

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Main Authors: Deliyanni E., Bakoyannakis D., Zouboulis A., Matis K.
Format: Article
Language:English
Published: Technical Faculty, Bor 2004-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2004/1450-53390401001D.pdf
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author Deliyanni E.
Bakoyannakis D.
Zouboulis A.
Matis K.
author_facet Deliyanni E.
Bakoyannakis D.
Zouboulis A.
Matis K.
author_sort Deliyanni E.
collection DOAJ
description The application of an innovative, simple and low cost method was tested for the preparation of nanocrystalline iron hydroxides and oxyhydroxides; different iron precursors have been earlier used and combined to different volatile precipitating agents. The examined in the present product, akaganéite [â-FeO(OH)], had high surface area and definite pore size distribution. The produced materials were examined in detail (i.e. by powder X-ray diffraction, TEM and nitrogen sorption measurement). Main aim of this study was to evaluate the efficiency of the prepared material in the removal of heavy and toxic metal cations, like Cd(II), from aqueous solutions; cadmium constitutes a priority pollutant. Sorption was found to depended on the solution pH and its ionic strength. Typical isotherm models were applied and calculated the values of maximum adsorbent capacity for the metal as well as that of the enthalpy change during the removal process.
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spelling doaj.art-b4ce710ffc4a4d428b6c70b687efb26d2022-12-21T21:09:07ZengTechnical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392004-01-014011910.2298/JMMB0401001DDevelopment and study of iron-based nanoadsorbentsDeliyanni E.Bakoyannakis D.Zouboulis A.Matis K.The application of an innovative, simple and low cost method was tested for the preparation of nanocrystalline iron hydroxides and oxyhydroxides; different iron precursors have been earlier used and combined to different volatile precipitating agents. The examined in the present product, akaganéite [â-FeO(OH)], had high surface area and definite pore size distribution. The produced materials were examined in detail (i.e. by powder X-ray diffraction, TEM and nitrogen sorption measurement). Main aim of this study was to evaluate the efficiency of the prepared material in the removal of heavy and toxic metal cations, like Cd(II), from aqueous solutions; cadmium constitutes a priority pollutant. Sorption was found to depended on the solution pH and its ionic strength. Typical isotherm models were applied and calculated the values of maximum adsorbent capacity for the metal as well as that of the enthalpy change during the removal process.http://www.doiserbia.nb.rs/img/doi/1450-5339/2004/1450-53390401001D.pdfakaganéitecadmiumadsorptionwastewater
spellingShingle Deliyanni E.
Bakoyannakis D.
Zouboulis A.
Matis K.
Development and study of iron-based nanoadsorbents
Journal of Mining and Metallurgy. Section B: Metallurgy
akaganéite
cadmium
adsorption
wastewater
title Development and study of iron-based nanoadsorbents
title_full Development and study of iron-based nanoadsorbents
title_fullStr Development and study of iron-based nanoadsorbents
title_full_unstemmed Development and study of iron-based nanoadsorbents
title_short Development and study of iron-based nanoadsorbents
title_sort development and study of iron based nanoadsorbents
topic akaganéite
cadmium
adsorption
wastewater
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2004/1450-53390401001D.pdf
work_keys_str_mv AT deliyannie developmentandstudyofironbasednanoadsorbents
AT bakoyannakisd developmentandstudyofironbasednanoadsorbents
AT zouboulisa developmentandstudyofironbasednanoadsorbents
AT matisk developmentandstudyofironbasednanoadsorbents