Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage
Iron catalyzed coupling of β-amino alcohols with allylic alcohols for the synthesis of 3,4-dihydro-2H-pyrrole derivatives has been developed. Mechanistic studies suggest that the reaction involves iron catalyzed dehydrogenative coupling and C–C bond cleavage processes.
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co. Ltd.
2021-08-01
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| Series: | Green Synthesis and Catalysis |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666554921000387 |
| _version_ | 1819020890882441216 |
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| author | Suya Cui Xiaoyun Wu Wei Ma Weijun Tang Huaming Sun Jianliang Xiao Dong Xue Chao Wang |
| author_facet | Suya Cui Xiaoyun Wu Wei Ma Weijun Tang Huaming Sun Jianliang Xiao Dong Xue Chao Wang |
| author_sort | Suya Cui |
| collection | DOAJ |
| description | Iron catalyzed coupling of β-amino alcohols with allylic alcohols for the synthesis of 3,4-dihydro-2H-pyrrole derivatives has been developed. Mechanistic studies suggest that the reaction involves iron catalyzed dehydrogenative coupling and C–C bond cleavage processes. |
| first_indexed | 2024-12-21T03:58:24Z |
| format | Article |
| id | doaj.art-b4d927c12ac3459ea1f659c8bf80c29d |
| institution | Directory Open Access Journal |
| issn | 2666-5549 |
| language | English |
| last_indexed | 2024-12-21T03:58:24Z |
| publishDate | 2021-08-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Synthesis and Catalysis |
| spelling | doaj.art-b4d927c12ac3459ea1f659c8bf80c29d2022-12-21T19:16:46ZengKeAi Communications Co. Ltd.Green Synthesis and Catalysis2666-55492021-08-0123307310Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavageSuya Cui0Xiaoyun Wu1Wei Ma2Weijun Tang3Huaming Sun4Jianliang Xiao5Dong Xue6Chao Wang7Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, ChinaKey Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, ChinaKey Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, ChinaKey Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, ChinaKey Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, ChinaDepartment of Chemistry, University of Liverpool, Liverpool L69 7ZD, United KingdomKey Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China; Corresponding authors.Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China; Corresponding authors.Iron catalyzed coupling of β-amino alcohols with allylic alcohols for the synthesis of 3,4-dihydro-2H-pyrrole derivatives has been developed. Mechanistic studies suggest that the reaction involves iron catalyzed dehydrogenative coupling and C–C bond cleavage processes.http://www.sciencedirect.com/science/article/pii/S2666554921000387Iron catalysisDehydrogenationCouplingC–C bond cleavageN-heterocycle |
| spellingShingle | Suya Cui Xiaoyun Wu Wei Ma Weijun Tang Huaming Sun Jianliang Xiao Dong Xue Chao Wang Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage Green Synthesis and Catalysis Iron catalysis Dehydrogenation Coupling C–C bond cleavage N-heterocycle |
| title | Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage |
| title_full | Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage |
| title_fullStr | Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage |
| title_full_unstemmed | Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage |
| title_short | Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage |
| title_sort | synthesis of 2h pyrroles via iron catalyzed dehydrogenative coupling and c c bond cleavage |
| topic | Iron catalysis Dehydrogenation Coupling C–C bond cleavage N-heterocycle |
| url | http://www.sciencedirect.com/science/article/pii/S2666554921000387 |
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