Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells

Perovskite is a promising light harvester for use in photovoltaic solar cells. In recent years, the power conversion efficiency of perovskite solar cells has been dramatically increased, making them a competitive source of renewable energy. An important parameter when designing high efficiency perov...

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Main Authors: Bat-El Cohen, Shany Gamliel, Lioz Etgar
Format: Article
Language:English
Published: AIP Publishing LLC 2014-08-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4885548
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author Bat-El Cohen
Shany Gamliel
Lioz Etgar
author_facet Bat-El Cohen
Shany Gamliel
Lioz Etgar
author_sort Bat-El Cohen
collection DOAJ
description Perovskite is a promising light harvester for use in photovoltaic solar cells. In recent years, the power conversion efficiency of perovskite solar cells has been dramatically increased, making them a competitive source of renewable energy. An important parameter when designing high efficiency perovskite-based solar cells is the perovskite deposition, which must be performed to create complete coverage and optimal film thickness. This paper describes an in-depth study on two-step deposition, separating the perovskite deposition into two precursors. The effects of spin velocity, annealing temperature, dipping time, and methylammonium iodide concentration on the photovoltaic performance are studied. Observations include that current density is affected by changing the spin velocity, while the fill factor changes mainly due to the dipping time and methylammonium iodide concentration. Interestingly, the open circuit voltage is almost unaffected by these parameters. Hole conductor free perovskite solar cells are used in this work, in order to minimize other possible effects. This study provides better understanding and control over the perovskite deposition through highly efficient, low-cost perovskite-based solar cells.
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spelling doaj.art-b4e47bea7b794abab3aea80fe571c3242022-12-22T00:02:24ZengAIP Publishing LLCAPL Materials2166-532X2014-08-0128081502081502-810.1063/1.4885548003491APMParameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cellsBat-El Cohen0Shany Gamliel1Lioz Etgar2Institute of Chemistry, Casali Center for Applied Chemistry, The Hebrew University of Jerusalem, Jerusalem 90400, IsraelInstitute of Chemistry, Casali Center for Applied Chemistry, The Hebrew University of Jerusalem, Jerusalem 90400, IsraelInstitute of Chemistry, Casali Center for Applied Chemistry, The Hebrew University of Jerusalem, Jerusalem 90400, IsraelPerovskite is a promising light harvester for use in photovoltaic solar cells. In recent years, the power conversion efficiency of perovskite solar cells has been dramatically increased, making them a competitive source of renewable energy. An important parameter when designing high efficiency perovskite-based solar cells is the perovskite deposition, which must be performed to create complete coverage and optimal film thickness. This paper describes an in-depth study on two-step deposition, separating the perovskite deposition into two precursors. The effects of spin velocity, annealing temperature, dipping time, and methylammonium iodide concentration on the photovoltaic performance are studied. Observations include that current density is affected by changing the spin velocity, while the fill factor changes mainly due to the dipping time and methylammonium iodide concentration. Interestingly, the open circuit voltage is almost unaffected by these parameters. Hole conductor free perovskite solar cells are used in this work, in order to minimize other possible effects. This study provides better understanding and control over the perovskite deposition through highly efficient, low-cost perovskite-based solar cells.http://dx.doi.org/10.1063/1.4885548
spellingShingle Bat-El Cohen
Shany Gamliel
Lioz Etgar
Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells
APL Materials
title Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells
title_full Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells
title_fullStr Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells
title_full_unstemmed Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells
title_short Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells
title_sort parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite based solar cells
url http://dx.doi.org/10.1063/1.4885548
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