Adsorption of inorganic anionic contaminants on surfactant modified minerals
Organo-mineral complexes were obtained by treatment of aluminosilicate minerals (zeolite, bentonite and diatomaceous earth) with a primary amine (oleylamine) and an alkyl ammonium salt (stearyldimethylbenzyl ammonium chloride). The modification of the zeolite surface was carried out in two steps. Th...
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Format: | Article |
Language: | English |
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Serbian Chemical Society
2003-11-01
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Series: | Journal of the Serbian Chemical Society |
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Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol68/No11/V68-No11-07.pdf |
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author | MAGDALENA TOMASEVIC-CANOVIC ANA RADOSAVLJEVIC-MIHAJLOVIC JOVAN LEMIC ALEKSANDRA DAKOVIC ALEKSANDRA VUJAKOVIC |
author_facet | MAGDALENA TOMASEVIC-CANOVIC ANA RADOSAVLJEVIC-MIHAJLOVIC JOVAN LEMIC ALEKSANDRA DAKOVIC ALEKSANDRA VUJAKOVIC |
author_sort | MAGDALENA TOMASEVIC-CANOVIC |
collection | DOAJ |
description | Organo-mineral complexes were obtained by treatment of aluminosilicate minerals (zeolite, bentonite and diatomaceous earth) with a primary amine (oleylamine) and an alkyl ammonium salt (stearyldimethylbenzyl ammonium chloride). The modification of the zeolite surface was carried out in two steps. The first step was treatment of the zeolite with 2 M HCl. This acid treatment of the zeolite increased its affinity for neutral molecules such as surface-active amines. The second step of the modification was the adsorption of oleylamine on the acid treated zeolite. Four types of organo-mineral complexes were prepared and their anion adsorption properties were compared to those of organo-zeolite. The adsorption of sulphate, bichromate and dihydrogenphosphate anions on the organo-mineral complexes was investigated. The anion adsorption measurements showed that the most efficient adsorbent for anion water pollutants was the primary amine modified H+-form zeolite. |
first_indexed | 2024-04-12T14:42:52Z |
format | Article |
id | doaj.art-b4e8ce32008849f4a73bc58d33e864b5 |
institution | Directory Open Access Journal |
issn | 0352-5139 |
language | English |
last_indexed | 2024-04-12T14:42:52Z |
publishDate | 2003-11-01 |
publisher | Serbian Chemical Society |
record_format | Article |
series | Journal of the Serbian Chemical Society |
spelling | doaj.art-b4e8ce32008849f4a73bc58d33e864b52022-12-22T03:28:45ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392003-11-016811833841Adsorption of inorganic anionic contaminants on surfactant modified mineralsMAGDALENA TOMASEVIC-CANOVICANA RADOSAVLJEVIC-MIHAJLOVICJOVAN LEMICALEKSANDRA DAKOVICALEKSANDRA VUJAKOVICOrgano-mineral complexes were obtained by treatment of aluminosilicate minerals (zeolite, bentonite and diatomaceous earth) with a primary amine (oleylamine) and an alkyl ammonium salt (stearyldimethylbenzyl ammonium chloride). The modification of the zeolite surface was carried out in two steps. The first step was treatment of the zeolite with 2 M HCl. This acid treatment of the zeolite increased its affinity for neutral molecules such as surface-active amines. The second step of the modification was the adsorption of oleylamine on the acid treated zeolite. Four types of organo-mineral complexes were prepared and their anion adsorption properties were compared to those of organo-zeolite. The adsorption of sulphate, bichromate and dihydrogenphosphate anions on the organo-mineral complexes was investigated. The anion adsorption measurements showed that the most efficient adsorbent for anion water pollutants was the primary amine modified H+-form zeolite.http://www.shd.org.yu/HtDocs/SHD/Vol68/No11/V68-No11-07.pdfzeolitebentonitediatomaceous eartholeylamineadsorptionanions |
spellingShingle | MAGDALENA TOMASEVIC-CANOVIC ANA RADOSAVLJEVIC-MIHAJLOVIC JOVAN LEMIC ALEKSANDRA DAKOVIC ALEKSANDRA VUJAKOVIC Adsorption of inorganic anionic contaminants on surfactant modified minerals Journal of the Serbian Chemical Society zeolite bentonite diatomaceous earth oleylamine adsorption anions |
title | Adsorption of inorganic anionic contaminants on surfactant modified minerals |
title_full | Adsorption of inorganic anionic contaminants on surfactant modified minerals |
title_fullStr | Adsorption of inorganic anionic contaminants on surfactant modified minerals |
title_full_unstemmed | Adsorption of inorganic anionic contaminants on surfactant modified minerals |
title_short | Adsorption of inorganic anionic contaminants on surfactant modified minerals |
title_sort | adsorption of inorganic anionic contaminants on surfactant modified minerals |
topic | zeolite bentonite diatomaceous earth oleylamine adsorption anions |
url | http://www.shd.org.yu/HtDocs/SHD/Vol68/No11/V68-No11-07.pdf |
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