Adsorption of inorganic anionic contaminants on surfactant modified minerals

Organo-mineral complexes were obtained by treatment of aluminosilicate minerals (zeolite, bentonite and diatomaceous earth) with a primary amine (oleylamine) and an alkyl ammonium salt (stearyldimethylbenzyl ammonium chloride). The modification of the zeolite surface was carried out in two steps. Th...

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Main Authors: MAGDALENA TOMASEVIC-CANOVIC, ANA RADOSAVLJEVIC-MIHAJLOVIC, JOVAN LEMIC, ALEKSANDRA DAKOVIC, ALEKSANDRA VUJAKOVIC
Format: Article
Language:English
Published: Serbian Chemical Society 2003-11-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol68/No11/V68-No11-07.pdf
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author MAGDALENA TOMASEVIC-CANOVIC
ANA RADOSAVLJEVIC-MIHAJLOVIC
JOVAN LEMIC
ALEKSANDRA DAKOVIC
ALEKSANDRA VUJAKOVIC
author_facet MAGDALENA TOMASEVIC-CANOVIC
ANA RADOSAVLJEVIC-MIHAJLOVIC
JOVAN LEMIC
ALEKSANDRA DAKOVIC
ALEKSANDRA VUJAKOVIC
author_sort MAGDALENA TOMASEVIC-CANOVIC
collection DOAJ
description Organo-mineral complexes were obtained by treatment of aluminosilicate minerals (zeolite, bentonite and diatomaceous earth) with a primary amine (oleylamine) and an alkyl ammonium salt (stearyldimethylbenzyl ammonium chloride). The modification of the zeolite surface was carried out in two steps. The first step was treatment of the zeolite with 2 M HCl. This acid treatment of the zeolite increased its affinity for neutral molecules such as surface-active amines. The second step of the modification was the adsorption of oleylamine on the acid treated zeolite. Four types of organo-mineral complexes were prepared and their anion adsorption properties were compared to those of organo-zeolite. The adsorption of sulphate, bichromate and dihydrogenphosphate anions on the organo-mineral complexes was investigated. The anion adsorption measurements showed that the most efficient adsorbent for anion water pollutants was the primary amine modified H+-form zeolite.
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spelling doaj.art-b4e8ce32008849f4a73bc58d33e864b52022-12-22T03:28:45ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392003-11-016811833841Adsorption of inorganic anionic contaminants on surfactant modified mineralsMAGDALENA TOMASEVIC-CANOVICANA RADOSAVLJEVIC-MIHAJLOVICJOVAN LEMICALEKSANDRA DAKOVICALEKSANDRA VUJAKOVICOrgano-mineral complexes were obtained by treatment of aluminosilicate minerals (zeolite, bentonite and diatomaceous earth) with a primary amine (oleylamine) and an alkyl ammonium salt (stearyldimethylbenzyl ammonium chloride). The modification of the zeolite surface was carried out in two steps. The first step was treatment of the zeolite with 2 M HCl. This acid treatment of the zeolite increased its affinity for neutral molecules such as surface-active amines. The second step of the modification was the adsorption of oleylamine on the acid treated zeolite. Four types of organo-mineral complexes were prepared and their anion adsorption properties were compared to those of organo-zeolite. The adsorption of sulphate, bichromate and dihydrogenphosphate anions on the organo-mineral complexes was investigated. The anion adsorption measurements showed that the most efficient adsorbent for anion water pollutants was the primary amine modified H+-form zeolite.http://www.shd.org.yu/HtDocs/SHD/Vol68/No11/V68-No11-07.pdfzeolitebentonitediatomaceous eartholeylamineadsorptionanions
spellingShingle MAGDALENA TOMASEVIC-CANOVIC
ANA RADOSAVLJEVIC-MIHAJLOVIC
JOVAN LEMIC
ALEKSANDRA DAKOVIC
ALEKSANDRA VUJAKOVIC
Adsorption of inorganic anionic contaminants on surfactant modified minerals
Journal of the Serbian Chemical Society
zeolite
bentonite
diatomaceous earth
oleylamine
adsorption
anions
title Adsorption of inorganic anionic contaminants on surfactant modified minerals
title_full Adsorption of inorganic anionic contaminants on surfactant modified minerals
title_fullStr Adsorption of inorganic anionic contaminants on surfactant modified minerals
title_full_unstemmed Adsorption of inorganic anionic contaminants on surfactant modified minerals
title_short Adsorption of inorganic anionic contaminants on surfactant modified minerals
title_sort adsorption of inorganic anionic contaminants on surfactant modified minerals
topic zeolite
bentonite
diatomaceous earth
oleylamine
adsorption
anions
url http://www.shd.org.yu/HtDocs/SHD/Vol68/No11/V68-No11-07.pdf
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AT jovanlemic adsorptionofinorganicanioniccontaminantsonsurfactantmodifiedminerals
AT aleksandradakovic adsorptionofinorganicanioniccontaminantsonsurfactantmodifiedminerals
AT aleksandravujakovic adsorptionofinorganicanioniccontaminantsonsurfactantmodifiedminerals