Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction Furnace

A high titania slag that is used as a feedstock for TiO<sub>2</sub> manufacturing is obtained by ilmenite smelting (FeO.TiO<sub>2</sub>). The composition of the slag obtained by smelting is dependent on the composition of the mineral used for slag preparation, i.e., ilmenite...

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Main Authors: Avishek Kumar Gupta, Matti Aula, Jouni Pihlasalo, Pasi Mäkelä, Marko Huttula, Timo Fabritius
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/3/1153
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author Avishek Kumar Gupta
Matti Aula
Jouni Pihlasalo
Pasi Mäkelä
Marko Huttula
Timo Fabritius
author_facet Avishek Kumar Gupta
Matti Aula
Jouni Pihlasalo
Pasi Mäkelä
Marko Huttula
Timo Fabritius
author_sort Avishek Kumar Gupta
collection DOAJ
description A high titania slag that is used as a feedstock for TiO<sub>2</sub> manufacturing is obtained by ilmenite smelting (FeO.TiO<sub>2</sub>). The composition of the slag obtained by smelting is dependent on the composition of the mineral used for slag preparation, i.e., ilmenite in our study. At the laboratory scale, ilmenite slags are mostly obtained by using ilmenite as the raw material. An easy and simple way would be to prepare the synthetic slag using the individual components and heating them to high temperature in a furnace. The titania slag has a high oxidizing nature and requires an inert atmosphere to prevent oxidation of the slag as well as the molybdenum crucible. This paper describes the preparation of synthetic ilmenite slag using an induction furnace and the study of the composition and the phases formed in the slag. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and inductively coupled plasma-optical emission spectroscopy (ICP-OES) were used as analytical techniques for studying the slag. A comparison between obtained synthetic slag and industrial ilmenite slag was performed to test the possibility of preparing slags in the laboratory as per the required composition. The slags show similar phase formation as obtained in industrial ilmenite slags, which means that the synthetic slags are identical to the industrial slags.
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spelling doaj.art-b4f73d76ac304b45950082281e0427e42023-12-03T14:50:52ZengMDPI AGApplied Sciences2076-34172021-01-01113115310.3390/app11031153Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction FurnaceAvishek Kumar Gupta0Matti Aula1Jouni Pihlasalo2Pasi Mäkelä3Marko Huttula4Timo Fabritius5Process Metallurgy Research Unit, University of Oulu, P.O. Box 4300, FI-90014, 90570 Oulu, FinlandProcess Metallurgy Research Unit, University of Oulu, P.O. Box 4300, FI-90014, 90570 Oulu, FinlandMetso Outotec Research Center, Kuparitie 10, 28330 Pori, FinlandMetso Outotec Research Center, Kuparitie 10, 28330 Pori, FinlandNano and Molecular Systems Research Unit, University of Oulu, P.O. Box 4300, FI-90014, 90570 Oulu, FinlandProcess Metallurgy Research Unit, University of Oulu, P.O. Box 4300, FI-90014, 90570 Oulu, FinlandA high titania slag that is used as a feedstock for TiO<sub>2</sub> manufacturing is obtained by ilmenite smelting (FeO.TiO<sub>2</sub>). The composition of the slag obtained by smelting is dependent on the composition of the mineral used for slag preparation, i.e., ilmenite in our study. At the laboratory scale, ilmenite slags are mostly obtained by using ilmenite as the raw material. An easy and simple way would be to prepare the synthetic slag using the individual components and heating them to high temperature in a furnace. The titania slag has a high oxidizing nature and requires an inert atmosphere to prevent oxidation of the slag as well as the molybdenum crucible. This paper describes the preparation of synthetic ilmenite slag using an induction furnace and the study of the composition and the phases formed in the slag. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and inductively coupled plasma-optical emission spectroscopy (ICP-OES) were used as analytical techniques for studying the slag. A comparison between obtained synthetic slag and industrial ilmenite slag was performed to test the possibility of preparing slags in the laboratory as per the required composition. The slags show similar phase formation as obtained in industrial ilmenite slags, which means that the synthetic slags are identical to the industrial slags.https://www.mdpi.com/2076-3417/11/3/1153ilmenitepyrometallurgytitania slagsmeltingpseudobrookite
spellingShingle Avishek Kumar Gupta
Matti Aula
Jouni Pihlasalo
Pasi Mäkelä
Marko Huttula
Timo Fabritius
Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction Furnace
Applied Sciences
ilmenite
pyrometallurgy
titania slag
smelting
pseudobrookite
title Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction Furnace
title_full Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction Furnace
title_fullStr Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction Furnace
title_full_unstemmed Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction Furnace
title_short Preparation of Synthetic Titania Slag Relevant to the Industrial Smelting Process Using an Induction Furnace
title_sort preparation of synthetic titania slag relevant to the industrial smelting process using an induction furnace
topic ilmenite
pyrometallurgy
titania slag
smelting
pseudobrookite
url https://www.mdpi.com/2076-3417/11/3/1153
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