Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf]
A new and efficient method for the synthesis of lactones and esters involving the application of an molecular oxygen-based electro-catalytic oxidation system and ionic liquid [bmim][OTf] as electrolyte has been developed. The reaction between various ketones with molecular oxygen proceeds in a three...
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| Format: | Article |
| Language: | English |
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Chemical Society of Ethiopia
2016-08-01
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| Series: | Bulletin of the Chemical Society of Ethiopia |
| Subjects: | |
| Online Access: | https://www.ajol.info/index.php/bcse/article/view/140946 |
| _version_ | 1811305037624770560 |
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| author | Y. L. Hu Y. B. Xie D. J. Li |
| author_facet | Y. L. Hu Y. B. Xie D. J. Li |
| author_sort | Y. L. Hu |
| collection | DOAJ |
| description | A new and efficient method for the synthesis of lactones and esters involving the application of an molecular oxygen-based electro-catalytic oxidation system and ionic liquid [bmim][OTf] as electrolyte has been developed. The reaction between various ketones with molecular oxygen proceeds in a three-electrode cell under constant current conditions in [bmim][OTf] at room temperature to give the corresponding esters and lactones in good to excellent isolated yield. Additionally, the possible mechanism of Baeyer-Villiger oxidation of ketones in the electro-catalytic system is proposed. |
| first_indexed | 2024-04-13T08:19:29Z |
| format | Article |
| id | doaj.art-b4ffe2930ce54d2aa14d1f93b665af35 |
| institution | Directory Open Access Journal |
| issn | 1011-3924 1726-801X |
| language | English |
| last_indexed | 2024-04-13T08:19:29Z |
| publishDate | 2016-08-01 |
| publisher | Chemical Society of Ethiopia |
| record_format | Article |
| series | Bulletin of the Chemical Society of Ethiopia |
| spelling | doaj.art-b4ffe2930ce54d2aa14d1f93b665af352022-12-22T02:54:42ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2016-08-01302297306http://dx.doi.org/10.4314/bcse.v30i2.14Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf]Y. L. HuY. B. XieD. J. LiA new and efficient method for the synthesis of lactones and esters involving the application of an molecular oxygen-based electro-catalytic oxidation system and ionic liquid [bmim][OTf] as electrolyte has been developed. The reaction between various ketones with molecular oxygen proceeds in a three-electrode cell under constant current conditions in [bmim][OTf] at room temperature to give the corresponding esters and lactones in good to excellent isolated yield. Additionally, the possible mechanism of Baeyer-Villiger oxidation of ketones in the electro-catalytic system is proposed.https://www.ajol.info/index.php/bcse/article/view/140946Baeyer-Villiger oxidationKetoneMolecular oxygenElectrocatalysisIonic liquid |
| spellingShingle | Y. L. Hu Y. B. Xie D. J. Li Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf] Bulletin of the Chemical Society of Ethiopia Baeyer-Villiger oxidation Ketone Molecular oxygen Electrocatalysis Ionic liquid |
| title | Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf] |
| title_full | Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf] |
| title_fullStr | Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf] |
| title_full_unstemmed | Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf] |
| title_short | Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf] |
| title_sort | efficient baeyer villiger electro oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid bmim otf |
| topic | Baeyer-Villiger oxidation Ketone Molecular oxygen Electrocatalysis Ionic liquid |
| url | https://www.ajol.info/index.php/bcse/article/view/140946 |
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