On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing

Nanogratings (NGs) are self-assembled subwavelength and birefringent nanostructures created by femtosecond laser direct writing (FLDW) in glass, which are of high interest for photonics, sensing, five-dimensional (5D) optical data storage, or microfluidics applications. In this work, NG formation wi...

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Main Authors: Qiong Xie, Maxime Cavillon, Diego Pugliese, Davide Janner, Bertrand Poumellec, Matthieu Lancry
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/17/2986
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author Qiong Xie
Maxime Cavillon
Diego Pugliese
Davide Janner
Bertrand Poumellec
Matthieu Lancry
author_facet Qiong Xie
Maxime Cavillon
Diego Pugliese
Davide Janner
Bertrand Poumellec
Matthieu Lancry
author_sort Qiong Xie
collection DOAJ
description Nanogratings (NGs) are self-assembled subwavelength and birefringent nanostructures created by femtosecond laser direct writing (FLDW) in glass, which are of high interest for photonics, sensing, five-dimensional (5D) optical data storage, or microfluidics applications. In this work, NG formation windows were investigated in nine commercial glasses and as a function of glass viscosity and chemical composition. The NG windows were studied in an energy—frequency laser parameter landscape and characterized by polarizing optical microscopy and scanning electron microscopy (SEM). Pure silica glass (Suprasil) exhibits the largest NG window, whereas alkali borosilicate glasses (7059 and BK7) present the smallest one. Moreover, the NG formation windows progressively reduced in the following order: ULE, GeO<sub>2</sub>, B33, AF32, and Eagle XG. The NG formation window in glasses was found to decrease with the increase of alkali and alkaline earth content and was correlated to the temperature dependence of the viscosity in these glasses. This work provides guidelines to the formation of NGs in commercial oxide glasses by FLDW.
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spelling doaj.art-b51aab5089894432b26e87467a05cc462023-11-23T13:48:56ZengMDPI AGNanomaterials2079-49912022-08-011217298610.3390/nano12172986On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct WritingQiong Xie0Maxime Cavillon1Diego Pugliese2Davide Janner3Bertrand Poumellec4Matthieu Lancry5Institut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceDepartment of Electronics and Telecommunications, Politecnico di Torino, 10129 Torino, ItalyDepartment of Applied Science and Technology (DISAT) and RU INSTM, Politecnico di Torino, 10129 Torino, ItalyInstitut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceNanogratings (NGs) are self-assembled subwavelength and birefringent nanostructures created by femtosecond laser direct writing (FLDW) in glass, which are of high interest for photonics, sensing, five-dimensional (5D) optical data storage, or microfluidics applications. In this work, NG formation windows were investigated in nine commercial glasses and as a function of glass viscosity and chemical composition. The NG windows were studied in an energy—frequency laser parameter landscape and characterized by polarizing optical microscopy and scanning electron microscopy (SEM). Pure silica glass (Suprasil) exhibits the largest NG window, whereas alkali borosilicate glasses (7059 and BK7) present the smallest one. Moreover, the NG formation windows progressively reduced in the following order: ULE, GeO<sub>2</sub>, B33, AF32, and Eagle XG. The NG formation window in glasses was found to decrease with the increase of alkali and alkaline earth content and was correlated to the temperature dependence of the viscosity in these glasses. This work provides guidelines to the formation of NGs in commercial oxide glasses by FLDW.https://www.mdpi.com/2079-4991/12/17/2986nanogratingsbirefringencefemtosecond laser direct writingalkaliviscosity
spellingShingle Qiong Xie
Maxime Cavillon
Diego Pugliese
Davide Janner
Bertrand Poumellec
Matthieu Lancry
On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing
Nanomaterials
nanogratings
birefringence
femtosecond laser direct writing
alkali
viscosity
title On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing
title_full On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing
title_fullStr On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing
title_full_unstemmed On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing
title_short On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing
title_sort on the formation of nanogratings in commercial oxide glasses by femtosecond laser direct writing
topic nanogratings
birefringence
femtosecond laser direct writing
alkali
viscosity
url https://www.mdpi.com/2079-4991/12/17/2986
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