On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing
Nanogratings (NGs) are self-assembled subwavelength and birefringent nanostructures created by femtosecond laser direct writing (FLDW) in glass, which are of high interest for photonics, sensing, five-dimensional (5D) optical data storage, or microfluidics applications. In this work, NG formation wi...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2022-08-01
|
Series: | Nanomaterials |
Subjects: | |
Online Access: | https://www.mdpi.com/2079-4991/12/17/2986 |
_version_ | 1797493933316505600 |
---|---|
author | Qiong Xie Maxime Cavillon Diego Pugliese Davide Janner Bertrand Poumellec Matthieu Lancry |
author_facet | Qiong Xie Maxime Cavillon Diego Pugliese Davide Janner Bertrand Poumellec Matthieu Lancry |
author_sort | Qiong Xie |
collection | DOAJ |
description | Nanogratings (NGs) are self-assembled subwavelength and birefringent nanostructures created by femtosecond laser direct writing (FLDW) in glass, which are of high interest for photonics, sensing, five-dimensional (5D) optical data storage, or microfluidics applications. In this work, NG formation windows were investigated in nine commercial glasses and as a function of glass viscosity and chemical composition. The NG windows were studied in an energy—frequency laser parameter landscape and characterized by polarizing optical microscopy and scanning electron microscopy (SEM). Pure silica glass (Suprasil) exhibits the largest NG window, whereas alkali borosilicate glasses (7059 and BK7) present the smallest one. Moreover, the NG formation windows progressively reduced in the following order: ULE, GeO<sub>2</sub>, B33, AF32, and Eagle XG. The NG formation window in glasses was found to decrease with the increase of alkali and alkaline earth content and was correlated to the temperature dependence of the viscosity in these glasses. This work provides guidelines to the formation of NGs in commercial oxide glasses by FLDW. |
first_indexed | 2024-03-10T01:27:06Z |
format | Article |
id | doaj.art-b51aab5089894432b26e87467a05cc46 |
institution | Directory Open Access Journal |
issn | 2079-4991 |
language | English |
last_indexed | 2024-03-10T01:27:06Z |
publishDate | 2022-08-01 |
publisher | MDPI AG |
record_format | Article |
series | Nanomaterials |
spelling | doaj.art-b51aab5089894432b26e87467a05cc462023-11-23T13:48:56ZengMDPI AGNanomaterials2079-49912022-08-011217298610.3390/nano12172986On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct WritingQiong Xie0Maxime Cavillon1Diego Pugliese2Davide Janner3Bertrand Poumellec4Matthieu Lancry5Institut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceDepartment of Electronics and Telecommunications, Politecnico di Torino, 10129 Torino, ItalyDepartment of Applied Science and Technology (DISAT) and RU INSTM, Politecnico di Torino, 10129 Torino, ItalyInstitut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), Université Paris-Saclay, CNRS, 91405 Orsay, FranceNanogratings (NGs) are self-assembled subwavelength and birefringent nanostructures created by femtosecond laser direct writing (FLDW) in glass, which are of high interest for photonics, sensing, five-dimensional (5D) optical data storage, or microfluidics applications. In this work, NG formation windows were investigated in nine commercial glasses and as a function of glass viscosity and chemical composition. The NG windows were studied in an energy—frequency laser parameter landscape and characterized by polarizing optical microscopy and scanning electron microscopy (SEM). Pure silica glass (Suprasil) exhibits the largest NG window, whereas alkali borosilicate glasses (7059 and BK7) present the smallest one. Moreover, the NG formation windows progressively reduced in the following order: ULE, GeO<sub>2</sub>, B33, AF32, and Eagle XG. The NG formation window in glasses was found to decrease with the increase of alkali and alkaline earth content and was correlated to the temperature dependence of the viscosity in these glasses. This work provides guidelines to the formation of NGs in commercial oxide glasses by FLDW.https://www.mdpi.com/2079-4991/12/17/2986nanogratingsbirefringencefemtosecond laser direct writingalkaliviscosity |
spellingShingle | Qiong Xie Maxime Cavillon Diego Pugliese Davide Janner Bertrand Poumellec Matthieu Lancry On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing Nanomaterials nanogratings birefringence femtosecond laser direct writing alkali viscosity |
title | On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing |
title_full | On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing |
title_fullStr | On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing |
title_full_unstemmed | On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing |
title_short | On the Formation of Nanogratings in Commercial Oxide Glasses by Femtosecond Laser Direct Writing |
title_sort | on the formation of nanogratings in commercial oxide glasses by femtosecond laser direct writing |
topic | nanogratings birefringence femtosecond laser direct writing alkali viscosity |
url | https://www.mdpi.com/2079-4991/12/17/2986 |
work_keys_str_mv | AT qiongxie ontheformationofnanogratingsincommercialoxideglassesbyfemtosecondlaserdirectwriting AT maximecavillon ontheformationofnanogratingsincommercialoxideglassesbyfemtosecondlaserdirectwriting AT diegopugliese ontheformationofnanogratingsincommercialoxideglassesbyfemtosecondlaserdirectwriting AT davidejanner ontheformationofnanogratingsincommercialoxideglassesbyfemtosecondlaserdirectwriting AT bertrandpoumellec ontheformationofnanogratingsincommercialoxideglassesbyfemtosecondlaserdirectwriting AT matthieulancry ontheformationofnanogratingsincommercialoxideglassesbyfemtosecondlaserdirectwriting |